摘要
本论文报道了通过不同方法合成三苄基氯化锡,并对该化合物进行IR和1HNMR解析。通过4种方法的比较,发现运用以DMF为分散剂,加入I2和AlCl3为辅助催化试剂,镁粉为还原剂得到的三苄基氯化锡产率最高,达到95%,是有效合成三苄基氯化锡的方法适合于工业化生产。
Three different methods for synthesis of tribenzylchlorotin wais was reported.The product was confirmed by the characterization of IR andlHNMR, through comparing with four methods. It was found that used DMF as dispersant, added Iodine and aluminium chloride as auxiliary catalytic reagent and magnesium powder as reducing reagent, the production rate is highest, arrived to 95%.It is the effective synthesis method of tribenzylchlorotin and suitable for industrial production.
出处
《化学工程师》
CAS
2014年第5期1-3,65,共4页
Chemical Engineer
基金
国家自然科学基金资助项目(No.21076066)
黑龙江省自然科学基金(No.B201010)
黑龙江省教育厅面上项目(No.125 11595)
齐齐哈尔大学研究生创新科研项目(No.YJSCX2013-017X)
