期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

水淬冷法制备正极材料LiMnPO_4

Preparation of cathode material LiMnPO_4 by quenching method
下载PDF
导出
摘要 本文采用高温固相合成法合成LiMnPO4,通过用碳包覆法改变其电导率,并用水淬冷法与传统的自然冷却法制备。通过XRD,SEM和充放电测试等手段,发现水淬冷法制得LiMnPO4比自然冷却法所得材料的粒径要小,且首次放电比容量高。 LiMnPO4/C cathode material was synthesized by high temperature solid state method,and the effect of water quenching and common cooling mode on the microstructure and electrochemical performance of LiMnPO4/C was studied.X-ray diffraction（XRD）,scanning electron microscopy（SEM）,and charge-discharge test was used to study the LiMnPO4/C.The result of the experiment shows that the morphology of the samples by water quenching is smaller than that by common cooling mode.Therefore,the initial specific charge of the samples by water quenching is better than that by common cooling mode.
作者 张晓波
机构地区 哈尔滨庆缘电工材料股份有限公司
出处 《化学工程师》 CAS 2014年第6期77-79,共3页 Chemical Engineer
关键词 正极材料 LIMNPO4 淬冷 cathode material LiMnPO4 quenching method
分类号 TQ432.2 [化学工程]
  • 相关文献

参考文献5

  • 1H Liu,Q Cao,L Jetal Fu,et al.Doping effects of zinc on LiFePO4 cathode material for lithium ion batteries [ J ].Electrochemistry Com- munications.2006,8 ( 10 ): 1553-1557.
  • 2Guohua Li, Hideto Azuma, Masayuki Tohda.LiMnPO4 as the cathode for lithium batteries[ J ].Electrochemical and Solid-State Letters.2002, 5(6):A135-A137.
  • 3Guoying Chen,Thomas J Richardson.Thermal instability of O- livine-type LiMnPO4 cathodes [ J ].Journal of Power Sources.2010, 195(4):1221-1224.
  • 4Shyue Ping Ong,Anubhav Jain,Geoffroy Hautier,et al.Thermal stabilities of delithiated olivine MPO4(M=Fe, Mn) cathodes inves- tigated using first principles calculations [ J ] .Electrochemistry Communications.2010,12 ( 3 ) :427-430.
  • 5王志兴,李向群,常晓燕,郭华军,彭文杰,李新海,陈启元.锂离子电池橄榄石结构正极材料LiMnPO_4的合成与性能[J].中国有色金属学报,2008,18(4):660-665. 被引量：25

二级参考文献17

  • 1常晓燕,王志兴,李新海,匡琼,彭文杰,郭华军,张云河.锂离子电池正极材料LiMnPO_4的合成与性能[J].物理化学学报,2004,20(10):1249-1252. 被引量：15
  • 2王晓琼,李新海,王志兴,郭华军,彭文杰,刘凤举.锂离子电池正极材料LiFe_(0.9)Ni_(0.1)PO_4的合成与性能[J].中国有色金属学报,2006,16(4):739-745. 被引量：6
  • 3PADHI A K,NAJUNDASWAMY K S,GOODENOUGH J B.Phospho-olivines as positive-electrode materials for rechargeable lithium batteries[J].J Electrochem Soc,1997,144(4):1188-1194.
  • 4ZHU B Q,LI X H,WANG Z X,GUO H J.Novel synthesis of LiFePO4 by aqueous precipitation and carbothermal reduction[J].Materials Chemistry and Physics,2006,98(2/3):373-376.
  • 5PADHI A K,NAJUNDASWAMY K S,MASQUELIER C OKADA S,GOODENOUGH J B.Effect of structure on the Fe^3+/Fe^2+ redox couple in iron phosphates[J].J Electruehem Soc,1997,144(5):1609-1613.
  • 6AMINE K,YASUDA H,YAMACHI M.Olivine LiCoPO4 as 4.8 V electrode material for lithium batteries[J].Eiectrochem Solid-State Lett,2000,3(4):178-179.
  • 7YANG J,XU J.Synthesis and characterization of carbon-coated lithium transition metal phosphates LiMPO4 (M=Fe,Mn,Co,Ni) prepared via a nonaqueous sol-gel route[J].J Electrochem Soc,2006,153(4):A716-723.
  • 8ZHANG S S,ALLEN J L,XU K,Jew T R.Optimization of reaction condition for solid-state synthesis of LiFepO4-composite cathodes[J].] Power Sources,2005,147:234-240.
  • 9CHUNG S C,BLOKING J T,CHIANG Y M.Electronically conductive phospho-olivines as lithium storage electrodes[J].Nature Materials,2002,1(2):123-128.
  • 10PROSIN1 P P,LISI M,ZANE D,PASQUALI M.Determination of the chemical diffusion coefficient of lithium in LiFePO4[J].Solid State lonics,2002,148(1/2):45-51.

共引文献24

化学工程师
2014年 第6期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部