期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

两个基于4-(1H-1,2,4-三氮唑)苯甲酸的稀土配位聚合物的合成、晶体结构及荧光性质(英文) 被引量：2

Two Lanthanide Coordination Polymers Derived from 4-(1H-1,2,3-Triazol-1-yl) benzoic Acid: Synthesis, Crystal Structures, and Fluorescence
下载PDF
导出
摘要 以4-(1H-1,2,4-三氮唑)苯甲酸为配体,采用水热法合成了2种稀土配位聚合物[Tb(tbc3)(H2O)3]n(1)和{[Nd(tbc3)(H2O)3]·H2O}n(2)(Htbc=4-(1H-1,2,4-三氮唑)苯甲酸)。运用X-射线单晶衍射法对该配位聚合物进行了结构测定,并对其进行了元素分析、红外光谱、TG及荧光光谱表征。单晶结构表明,配位聚合物1为三斜晶系,空间群P1,配位聚合物2属于单斜晶系,空间群为P21/c。配位聚合物1和2均为一维链结构,均通过非共价键作用形成三维超分子构造。 Two lanthanide Coordination Polymers, [Tb（tbc3）（H2O）3]n （1H-1,2,3-triazol-l-yl） benzoic acid], have been synthesized （1） and {[Nd（tbc3）（H2O）3]·H2O}. （2）[Htbc=4- by hydrothermal method and structurally characterized by elemental analyses, FT-IR spectra, and thermal studies, fluorescence spectra, as well as single crystal X-ray diffraction. Structural determination reveals that complex 1 belongs to triclinic system and space group P1. And complex 2 crystallizes in monoclinic system, space group P2 1/c. Both 1 and 2 possess a one dimensional chain structure constructed from carboxylate O atoms of Htbe ligand bridging the units. Through non-covalent interactions the complex molecules are assembled into 3D supramolecular network structures.
作者 方智利 聂启祥 郑盛润 钟昀 熊姗
机构地区 华东交通大学基础学院 华南师范大学化学与环境学院
出处 《无机化学学报》 SCIE CAS CSCD 北大核心 2014年第7期1503-1510,共8页 Chinese Journal of Inorganic Chemistry
基金 国家自然科学基金(No.21365012)资助项目
关键词 稀土配位聚合物 4-(1H-1 2 4-三氮唑)苯甲酸 晶体结构 lanthanide coordination polymer 4-（1H-1,2,3-triazol-1-yl） benzoic acid crystal structure
分类号 O614.341 [理学—无机化学] O614.335 [理学—无机化学]
  • 相关文献

参考文献31

  • 1Hernendez I, Zheng Y X, Motevalli M, et al. Chem. Commun., 2013,49:1933-1935.
  • 2Xie S M, Zhang Z J, Wang Z Y, et al. J. Am. Chem. Soc., 2011,133:11892-11895.
  • 3Cheng Y, Kajiro H, Noguchi H, et al. Langmuir, 2011,27: 6905 -6909.
  • 4Park J, Kim H, Jung Y. J. Phys. Chem. Lett., 2013,4:2530- 2534.
  • 5FitzGerald S A, Pierce C J, Rowsell J L C, et al. J. Am.Chem. Soc., 2013,135:9458-9464.
  • 6Fang Z L, Zheng S R , Zhang W G, et al. Inorg. Chem. Commun., 2012,20:122-125.
  • 7Cai H, Guo Y, Li J G. Irtorg. Chem. Commun., 2013,34:37-41.
  • 8Aurel T, Claudio P, Ivan T, et al. Cryst. Growth Des., 2013, 13:3087-3097.
  • 9Hems W P, Groarke M, Zanotti-Gerosa A, et al. Aec. Chem. Res., 2007,40:1340-1347.
  • 10Ferguson A, Schmidtmann M, Brechin E K, et al. Dalton Trans., 2011,40:334-336.

二级参考文献17

  • 1YANG Juan(杨娟),DAI Jun(戴俊),LI Fei-Fei(李飞飞).Wuji Huaxue Xuebao,2010,26(9):1605-1611.
  • 2DAI Jun(戴俊),YANG Juan(杨娟),CHEN Xi(陈曦).Wuji Huaxue Xuebao,2011,27(8):1617-1624.
  • 3Kurmoo M. Chem. Soc. Rev. 2009,38:1353-1379.
  • 4Chun H J,Wang X H, Gao S, et al. Inorg. Chem., 2009,48:1301-1302.
  • 5Zhang M D, Di C M, Zheng H G. Inorg. Chem. Commun.,2013,27:88-91.
  • 6Zhang M D, Qin L, Yang H T, et al. Cryst. Growth. Des.2013,13:1961-1969.
  • 7Yang Q X,Chen X Q, Cui J H, et al. Cryst. Growth Des.,2012,12(8):4072-4082.
  • 8Yang Q X, Huang L F, Zhang M D, et al, Cryst. GrowthDes. 2013,13(2):440-445.
  • 9Qin L, Hu J S,Zhang M D, et al. Chem. Commun., 2012,48:10757-10759.
  • 10Allendorf M D, Bauer C A, Bhakta R K, et al. Chem. Soc.Rev., 2009,38:1330-1352.

共引文献8

同被引文献18

  • 1邓玉恒,王双研,刘娟,杨永丽,张帆,马宏伟.通过氢键构筑的含3-硝基邻苯二甲酸的层状超分子化合物[J].化学学报,2007,65(9):809-815. 被引量：5
  • 2FANG Z,BUEKEN B,DE VOS DE, et al. Defect-engi-neered metal-organic frameworks [ J ]. Angewandte Che-mie International Edition, 2015,54(25) : 7234-7254.
  • 3KORNIENKO N, ZHAO Y B,KLEY C S, et al. Metal-organic frameworks for electrocatalytic reduction of carbondioxide [ J ]. Journal of the American Chemical Society,2015, 137(44): 14129-14135.
  • 4OU Y C,WANG J, LENG J D, et al. Two new 1,2,4,5-cyclohexanetetracarboxylate-bridged frameworks with met-alhydroxide subunits. Synthesis, structures, magnetism andadsorption[ J]. Dalton Transactions, 2011, 40( 14) : 3592-3600.
  • 5LI T,LIU X,HUANG Z P, et al. Metal cation-depen-dent construction of two 3-D interpenetrating networksbased on the ligand 1-(4- carboxyphenyl )-1,2,4- tria-zole [ J ]. Inorganic Chemistry Communications, 2014,39: 70-74.
  • 6BENNION J C,MCBAIN AF, SONS, et al. Design andsynthesis of a series of nitrogen - rich energetic cocrystalsof 5,5,- dinitro - 2H,2H ’ -3,3,- bi - 1,2,4- triazole(DNBT)[J]. Crystal Growth & Design, 2015, 15(5):2545-2549.
  • 7DOUVAU A, PAPAEFSTATHIOU G S, GULLO M P, etal. Alkaline earth metal ion/dihydroxy-terephthalate MOFs:structural diversity and unusual luminescent properties[J].Inorganic Chemistry, 2015,54( 12) : 5813-5826.
  • 8ZHAO L, UU B T,JIN GH,et al. Diaquabisj 1-[(1H-benzimidazol-2-yl) -methyl] - 1H-1,2,4- triazole - kappaN-4| bis-(2,4,5 - tricarboxybenzoato - kappa 0-1) -cad-mium dehydrate [ J ]. Acta Crystallographica Section E -Structure Reports Online, 2012,68(Pt2) : ml39-ml40.
  • 9GAN X P, CHU M J,YAO J G,et al. Synthesis and crys-tal structure of charge separate manganese complex [ J ].Asian Journal of Chemistry, 2014,26( 15) : 257-260.
  • 10MU Y H, GE Z W, LI C P, et al. 3D pillared-layer co-ordination frameworks constructed from 4-( 1, 2,4-tria-zole) benzoic acid and different [ M ( HCOO ) ] layers [ J ].Inorganic Chemistry Communications, 2014, 48: 94-98.

引证文献2

二级引证文献2

无机化学学报
2014年 第7期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部