摘要
本文利用微分方程的等价性,从微圆盘电极上暂态可逆扩散方程的一般解出发,得到了耦合一级均相化学反应的可逆电极反应CE、EC、EC′和ECE的稳态电流计算公式。
In this paper. reversible microdisk electrode reactions with coupled first-order homogeneous chemical reactions are discussed, with the equivalence between the recombinated steady state diffusion equations and the Laplace transformed transient diffusion equation of simple electrode reactions. Expressions for steady state current of CE,EC,EC' and ECE reactions are derived with the help of the general solution presented before.
出处
《重庆师范学院学报（自然科学版）》
1993年第1期24-32,共9页
Journal of Chongqing Normal University(Natural Science Edition)
关键词
微圆盘电极
扩散方程
暂态
可逆
microdisk electrode, electrode reaction with coupled homoge-neous chemical reaction, steady state electrochemical behayiour
