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测定乙酸乙酯皂化反应速率常数的原理和方法 被引量:3

The principle and method of determining the rate constant for the reaction of the ethyl acetate saponification
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摘要 测定反应速率常数是高校化学专业学生必做的实验。本文以乙酸乙酯皂化反应为例 ,从测定原理和操作方法进行了介绍 。 To determine the rate constant of the reaction is an experiment done essentially by the students majoring in chemistry in college. In this article, it is introduced from the determination principles and operation methods with an example of the ethyl acetate soponification, and especially gives a detailed analysis of the relation between the concentration change of the electrolyte ion and the conductance rate in solution.
作者 曹楠
出处 《枣庄师专学报》 2000年第2期60-61,63,共3页 Journal of Zaozhuang Teachers' College
关键词 乙酸乙酯 反应速率常数 电导率 皂化反应 离子浓度 测定原理 测定方法 the ethyl acetate the rate constant of the reaction the conductance rate.
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同被引文献21

  • 1桑(艹桑).“酯的水解”实验的改进[J].化学教学,1992(2):26-26. 被引量:2
  • 2马军营.羧酸酯水解的类型及影响因素[J].信阳师范学院学报(自然科学版),1998,11(4):417-421. 被引量:12
  • 3Xing X P, Wang L C. Determination of rate constants and activation energy of 3-chloro-1, 2- propanedlol hydrolysis by capillary electrophoresis with electrochemical detection [J]. Journal of Chromatography A, 2005,1072:267-272.
  • 4Zhang L, Tong P, Chen G N. Determination of the hydrolysis rate constants and activationenergy of aesculin with capillary electrophoresis end-column amperometric detection [J]. Journal of Chromatography A, 2005, 1098: 194-198.
  • 5Chen G, Bao H M, Yang P Y. Determination of the rate constants and activation energy of acetaminophen hydrolysis by capillary electrophoresis[J]. Journal of Pharmaceutical and Biomedical Analysis, 2002, 29:843 - 850.
  • 6Ding X, Zhang X, Ye J. Capillary electrophoresis as a method for determining the hydrolysis rate constant of raffinose[J]. J Capillary Electrophor, 2002, 7 (3, 4) : 87-90.
  • 7Lan Zhang, Ping Tong Guonan Chen. Determination of the hydrolysis rate constants and activation energy of aesculin with capillary electrophoresis end-column amperometric detection [J]. Journal of Chromatography A, 2005, 1098:194-198.
  • 8武汉大学.无机化学[M].上册.北京:高等教育出版社,1998.312-316.
  • 9杨彦芳.对酯水解反应实验的改进[J].延安大学学报(自然科学版),1997,16(4):91-91. 被引量:1
  • 10苏培峰,谭凯,吴安安,吕鑫,赵仪,曹泽星,吴玮.理论与计算化学研究进展[J].厦门大学学报(自然科学版),2011,50(2):311-318. 被引量:17

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