摘要
本文报导了五个2,6—二甲酰基,4—甲基苯酚(DFMP)与氨基酸生成的西佛碱络合物的合成,并对这些络合物进行了红外、紫外、元素分析等表征分析;同时对两个铜络合物做了环电位扫描分析.
In the paper,we report the syntheses of five bimetal complexes of Schiff base which are obtained by the reaction between 2,6—diformyl,4—methylphenol(DFMP)and amino acid.We repeat- ed the reaction in which Okawa had failed to get the product and founded that the reaction proceeds as expected in the solution of alcohol and water.In the same time we identified these complexes by IR, UV,EA analyses and did the cycle valtammetry experiments.
关键词
氨基酸
西佛碱络合物
模板反应
amino acid
ligand compoud of Schiff base
template reaction
