摘要
本文用乙酰基二茂铁合成了α-二茂铁基乙叉富烯,将其锂化后分别与四氯化钛、三氯一茂钛、三氯(甲基茂)钛、二氯二茂钛反应,合成了四种含二茂铁基的有机钛化合物,并对这些化合物作了物理及化学性质的研究、元素分析、红外光谱和核磁共振谱的分析。
α-Ferrocenyl ethyl cyclopentadiene was synthesized from acetylferrocene,then lithiation by LiAlH_4.The Lithium compounds react with TiCl_4、CpTiCl_3、MeCpTiCl_3 and Cp_2TiCl_2 Separately. Tour ferro cenyl organic titanium compounds were obtained.The physical and chemical properties of these compounds have been studied.These compounds were identified by elementary analysis,IR and NMR spectra.
出处
《化学工程师》
CAS
1991年第2期15-17,共3页
Chemical Engineer
