摘要
在单脉冲激波管中,用对比速率法研究了TiCl_4的裂解。从自由基清扫剂环已烷C_6H_(12)的诱发裂解中产生的C_2H_4的测量,确定反应的机制,并测量得到了TiCl_4裂解初始过程的反应速率常数:k(TiCl_4→TiCl_3·+Cl·)=10^(16.4)exp(-(41700)/T)sec^(-1)。
The decomposition of TiCl_4 has been studied in a single pulse shock tube. Reaction extent is determined by measuring the ethylene yielded from the induced decomposition of the scavenger cyclohexane attacked by the TiCl_4 decomposition product Cl. The rate expression has been obtained k (TiCl_4→TiCl_3+Cl·)=10^(16.4)exp (-41,700/T) sec^(-1).
基金
国家自然科学基金
