摘要
以蚕沙糊状叶绿素经酸碱降解制得的二氢卟吩P6三甲酯(2)为关键中间体,设计合成了9个二氢卟吩P6醚类衍生物3a～3e和4b～4e,用UV、IR、1H NMR、FAB-MS和元素分析确证了它们的结构.
Nine chlorin P-6 ether derivatives (3a similar to 3e and 4b similar to 4e) were designed and synthesized via HBr addition of 2-vinyl of chlorin P-6 trimethylester (2), which was prepared through acidic and alkaline oxidative degradation using silkworm excrement crude chlorophyll extracts as a starting material followed by H-2 O, MeOH, EtOH, n - C-3 H-7 OH, CH2 double bond CHCH2OH nucleophilic substitution and hydrolysis respectively. All these compounds are previously unknown. Their structures were assigned based on the data derived from UV, IR, H-1 NMR, FAB-MS and elemental analysis.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2001年第6期458-462,共5页
Chinese Journal of Organic Chemistry
基金
国家自然科学基金
