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海绵Ircinia selaginea中一种罕见的长共轭二萜烯酮 被引量:1

A Rare Long Conjugated Diterpene Ketene from the Marine Sponge Ircinia selaginea(Lamark)
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摘要 A new diterpene, irciniketene, was isolated from the marine sponge Ircinia selaginea(Lamark) collected from the sea around Baihai, Guangxi Province. Its structure was determined by spectroscopic methods. In the structure, a ketene function is connected with a long conjugated system via an allene unit. Irciniketene shows a moderate inhibition toward MGC and HepG2 tumor cell lines. A new diterpene, irciniketene, was isolated from the marine sponge Ircinia selaginea(Lamark) collected from the sea around Baihai, Guangxi Province. Its structure was determined by spectroscopic methods. In the structure, a ketene function is connected with a long conjugated system via an allene unit. Irciniketene shows a moderate inhibition toward MGC and HepG2 tumor cell lines.
机构地区 中山大学化学系
出处 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2001年第6期949-951,共3页 Chemical Journal of Chinese Universities
基金 国家自然科学基金! (批准号 :2 992 0 3 0 2 9772 0 5 8)资助
关键词 海绵 IrciniaSelaginea 长共轭二萜烯酮 生物活性 肿瘤 化学结构 抑制作用 抗肿瘤药物 Marine sponge Ircinia selaginea Diterpene Ketene Biological activity
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参考文献3

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同被引文献5

  • 1Pettit R, Xu J P, Chapuis J C, et al. Antineoplastic Agents. 520. Isolation and Structure of Irciniastatins A and B from the Indo-Pacific Marine Sponge Ircinia Ramosa[ J]. J Med Chem, 2004,47 (5) : 1149-1152.
  • 2Hamad H. Issa, Juniehi Tanaka, Tatsuo H. New Cytotoxie Furanosesterterpenes from an Okinawan Marine Sponge, Ircinia sp. [J]. JNat Prod, 2003,66(1) :251-254.
  • 3Gopichand Y, Schmitz F J. Marine natural products:fistulatin-1 ,-2, and -3 from the sponge Aplysina fistularis forma fulva [J]. Tetrahedron Letters, 1979,41 (45) :3921-3924.
  • 4Abous-Shoer M I, Shaala L A, Youssef D T A. Bioactive brominated metabolites from the red sea sponge suberea mollis[ J]. J Nat Prod, 2008,71(8) :1464-1467.
  • 5Keman M R, Cambie R C. Chemistry of sponges, VII. 11, 19-dideoxyfistularin 3 and ll-hydroxyaerothionin, bromotyrosine derivatives from pseudocerayina durissima [ J ]. J Nat Prod, 1990,53(3) :6154522.

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