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电感耦合等离子体质谱法测定地质样品中铂、钯、钌、铑、铱和金 被引量:53

Determination of Pt, Pd, Ru, Rh, Ir and Au in Geological Samples By Double Focusing High Resolution Inductively Coupled Plasma Mass Spectrometry
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摘要 研究Te共沉淀分离富集、ICP-MS铂族元素和金测定方法。方法检出限 1~9 pg/g;回收率≥90%。国标GBW07288-GBW07294、加拿大WGB1及南非铂矿SARM7等标样分析表明:结果满意,方法可靠。 A method for the determination of Pt.Pd. Ru. Rh. Ir and Au in geological samples was studied. The sample was fused by sodium peroxide and determined by a double focusing high resolution inductively coupled plasma mass spectrometer 'ELEMENT' after the separation and enrichment by co-precipitation with Te. Detection limit of the method was between 1 -9ng/g and the recovery was > 90%. Our analytical results for some domestic or international reference materials were in agreement with the certified values.
出处 《分析化学》 SCIE EI CAS CSCD 北大核心 2001年第6期653-656,共4页 Chinese Journal of Analytical Chemistry
关键词 铂族元素 共沉淀 地质样品 电感耦合 等离子体质谱分析 测定 Platinum group element, co-precipitation, geological samples, inductively coupled plasma mass spectrometry
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