摘要
报道了在氯化铁(FeCI3·6H2O)催化剂存在下由苯甲酸和各种醇含成系列苯甲酸酯,测定了苯甲酸与醇的摩尔比在0.05:0.15(或0.20)下,反应时间为3.0h,FeC13·6H2O催化剂用量O.5Og的苯甲酸的转化率,测定了合成的苯甲酸酯的沸点、元素组成、红外光谱、核磁共振语。
Benzoic Esters were prepared from benzi0c acid and various alcohols in the presence ofFerric chloride FeCl,. 6H2O catalyst, The transition efficiency of benzioc acid was measuredunder mole ratio of benzi0c acid and various alcohols was O; O5: O. 15 (or 0. 2O), reactiontime of 3. Oh and amount of FeCl3. 6H2O cata1yst 0f O- 5Og. The properties of benzoic es-ters, such as boiling point, elementary component, IR(Infrared Spectroscopy) and HNMR(Nuclear Magnetie Resonance Spectroscopy) were measured.