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强碱阴离子交换树脂多相催化油脂的酯交换 被引量:36

Interesterification of Oils and Fats over Basic Anion Exchange Resin as Heterogeneous Catalyst
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摘要 Refined soybean oil and lard were interesterified in the presence of a basic anion exchange resin as heterogeneous catalyst. The structural composition of the interesterification products was determined by 1,3 specific lipase hydrolysis method followed by chromotographic analysis. The influences of the acidity of reactants, reaction time and reaction temperature on the interesterfication have been investigated. The experimental results showed that a mixture of 60% soybean oil and 40% lard(in mass ratio) with acid value of 0 116 was found to have remarkable interesterification at 50℃, for 150 min by using 10% basic anion exchange resin as a catalyst. The melting point of the final product was 37 6 ℃. Refined soybean oil and lard were interesterified in the presence of a basic anion exchange resin as heterogeneous catalyst. The structural composition of the interesterification products was determined by 1,3 specific lipase hydrolysis method followed by chromotographic analysis. The influences of the acidity of reactants, reaction time and reaction temperature on the interesterfication have been investigated. The experimental results showed that a mixture of 60% soybean oil and 40% lard(in mass ratio) with acid value of 0 116 was found to have remarkable interesterification at 50℃, for 150 min by using 10% basic anion exchange resin as a catalyst. The melting point of the final product was 37 6 ℃.
作者 谢文磊
出处 《应用化学》 CAS CSCD 北大核心 2001年第10期846-848,共3页 Chinese Journal of Applied Chemistry
关键词 强碱性阴离子交换树脂 催化剂 酯交换 油脂 多相催化 basic anion exchange resin,catalyst,interesterfication
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参考文献4

  • 1[1]Lo Y C,Handel A P. J Am Oils Chem Soc,1983,60(4) :815
  • 2[2]Laning S J. J Am Oils Chem Soc,1985,62(2):400
  • 3[3]Narangoni A G, Rousseau D. Trends Food Sci Technol, 1995, (6): 329
  • 4[4]Paquot C,Hautfenne A. Standard Methods for the Analysis of Oils, Fats and Derivatives, 7th Edn.California: Blackwell Scientific Publications Ltd,1987:111,130

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