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1,2-(1H-1,2,4-三唑)乙烷桥联Cu(Ⅱ)配合物的合成和研究 被引量:4

Synthesis and studies on 1,2-bis(1H-1,2,4-triazol-yl) ethane bridging Cu(Ⅱ) complexes
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摘要 以 1,2 - (1H - 1,2 ,4 -三唑 )乙烷为桥联配体 (L)和 [Cu(dien) ](ClO4) 2 ,Cu(en) 2 (ClO4) 2 反应 (dien为二乙烯三胺 ,en为乙二胺 ) ,得到二个一维链状配合物[Cu(dien)L](ClO4) 2 (1)和 [Cu(en) 2 L](ClO4) 2 (2 ) ,研究了配合物的组成、结构和性质 。 The reactions of 1,2 bis(1H 1,2,4 triazol yl) ethane (L) with (ClO 4) 2,Cu(en) 2(ClO 4) 2 (dien=dienthenetriamine,en=ethanediamine) form two one dimensional chain copper complexes (ClO 4) 2(1) and Cu(en) 2L(ClO 4) 2(2).The composition and properties on these complexes are studied and the single crystal structure is determined by x-ray diffraction method.
出处 《苏州大学学报(自然科学版)》 CAS 2001年第3期70-74,共5页 Journal of Soochow University(Natural Science Edition)
基金 江苏省有机合成重点实验室资助项目
关键词 铜配合物 桥联 合成 1 2-(1H-1 2 4-三唑)乙烷 晶体结构 化学组成 copper complexes triazole bridging synthesis
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同被引文献15

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