Two Interpenetrated and Polycatenated Zn(Ⅱ)Coordination Polymers:Syntheses,Structures and Luminescent Properties 被引量：1

Two Interpenetrated and Polycatenated Zn(Ⅱ) Coordination Polymers: Syntheses, Structures and Luminescent Properties

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摘要 Two fascinating Zn（II）entangled coordination polymers,[Zn（eoba）(bbi)];·nH;O（1）and[Zn（boba）(bbi);];（2）,(bbi=1,1?-（1,4-butanediyl）-bis（imidazole）,H;eoba=4,4?-（ethane-1,2-diyldioxy）-dibenzoic acid,H;boba=4,4?-（butane-1,4-diyldioxy）-dibenzoic acid),were obtained by hydrothermal technology and characterized by elemental analysis,infrared spectrum,thermogravimetric analysis and single-crystal X-ray diffraction.1 is a rare 2D→3D example with a 3-fold parallel interpenetration and polycatenaned architecture.2 features a scarce2D→2D example with a 3-fold parallel interpenetrating network which possesses polyrotaxane and polycatenane characters.Moreover,the luminescent properties of 1 and 2 have been discussed. Two fascinating Zn(II)entangled coordination polymers,[Zn(eoba)(bbi)]_n·nH_2O(1)and[Zn(boba)(bbi)_(1/2)]_n(2),(bbi=1,1?-(1,4-butanediyl)-bis(imidazole),H_2eoba=4,4?-(ethane-1,2-diyldioxy)-dibenzoic acid,H_2boba=4,4?-(butane-1,4-diyldioxy)-dibenzoic acid),were obtained by hydrothermal technology and characterized by elemental analysis,infrared spectrum,thermogravimetric analysis and single-crystal X-ray diffraction.1 is a rare 2D→3D example with a 3-fold parallel interpenetration and polycatenaned architecture.2 features a scarce2D→2D example with a 3-fold parallel interpenetrating network which possesses polyrotaxane and polycatenane characters.Moreover,the luminescent properties of 1 and 2 have been discussed.

作者吕丛陈琳刘博周实

机构地区 Key Laboratory of Preparation and Application of Environmental Friendly Materials(Jilin Normal University) Department of Chemistry

出处《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2018年第11期1786-1794,共9页 结构化学（英文）

基金 Supported by the Science and Technology Development plan of Jilin Province(20150520006JH) Science and Technology Research Project of Education Department of Jilin province(2016219,JJKH20180776KJ) Science and Technology Development plan of Siping City(2013055)

关键词 3-fold interpenetration luminescent property crystal structure 3-fold interpenetration luminescent property crystal structure

分类号 O641.4 [理学—物理化学]

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