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自固化脂肪族聚氨酯丙烯酸酯作为光敏齐聚体制备紫外光固化材料及其性能 被引量:3

Preparation and properties of the UV-curing material with aliphatic urethane acrylate as a photosensitive oligomer
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摘要 以自固化脂肪族聚氨酯丙烯酸酯(B-286c)、三丙二醇二丙烯酸酯(TPGDA)和2-甲基-1-(4-甲硫基苯基)-2-吗啉-1-丙酮(907)为原料制备了一系列自由基型紫外光固化材料,研究了齐聚物B-286c、稀释剂TPGDA、光引发剂907对紫外光固化膜的硬度、冲击性能、柔韧性能以及拉伸性能的影响。实验结果表明:在B-286c质量分数为76.5%,TPGDA质量分数为19%,907质量分数为4.5%时,所制备的紫外光固化材料的综合性能较好,其拉伸强度、断裂伸长率、冲击强度、阻尼硬度、柔韧性分别为:5.93MPa、13.4%、50kg·cm^(-1)、19%和1mm。 A series of the photosensitive coatings were prepared with the aliphatic urethane acrylate(B-286 c),tripropylene glycol diacrylate(TPGDA)and 2-methyl-1-(4-methylthiophenyl)-2-morpholino-1-propanone(907).The influences of every composition on the properties of photosensitive films were tested and analyzed.The experiment results showed that the tensile strength of the UV-curable films was 5.93 MPa,the elongation at break of the UV-curable films was 13.4%,the impact strength of the UV-curable films was 50 kg·cm-1,the damping hardness of the UV-curable films was 19%,and the flexibility of the UVcurable films was 1 mm when it was made of the optimum formulation in which the mass fraction of B-286 cwas 76.5%,the mass fraction of TPGDA was 19%,and the mass fraction of 907 was 4.5%.
作者 韩琳琳 黄笔武 HAN Linlin;HUANG Biwu(School of Material Science and Engineering,Nanchang University,Nanchang 330031,China)
出处 《南昌大学学报(理科版)》 CAS 北大核心 2018年第4期343-347,共5页 Journal of Nanchang University(Natural Science)
基金 国家自然科学基金资助项目(51563017)
关键词 紫外光固化 聚氨酯丙烯酸酯 齐聚体 性能 UV-curing urethane acrylate oligomer property
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