摘要
本文综述了近年来使用传统自由基聚合方法控制粒径单分散性的操作工艺特点。总结了新制备方法,包括膜乳化、共聚焦-微流化、电流体动力学喷雾、喷墨打印法、气溶胶-凝胶法、两亲聚合物的自组装及改进的Stber方法等,介绍了其原理、特点和研究现状。最后,提出了关于单分散聚合物微球合成发展的建议。
The characterization of operation to regulate the monodispersity was summarized with con- ventional radical polymerization method. And also, the principles, features and research status of newly emerging preparation methods, such as membrane emulfication, flow-focusing microfluidic method, electrohydrodynamic atomization, ink-jet printing, sol-gel method, self-assembling of am- phiphilic block polymer and the modified Stober method, etc. were reviewed. Finally, suggestion was proposed for further development of synthesis of monodisperse polymer microspheres.
出处
《材料工程》
EI
CAS
CSCD
北大核心
2014年第8期97-104,共8页
Journal of Materials Engineering
关键词
单分散
聚合物微球
共聚焦微流化
电流体动力学喷雾
自组装
monodisperse
polymer microsphere
flow-focusing microfluidic method
electrohydrodynamic atomization
self-assembling
