摘要
在水热条件下,成功合成出1例1D的新型草酸钴化合物—[Co(C2O4)0.5(H2O)]n(1).X-射线单晶衍射的分析表明,化合物(1)属于单斜晶系,C2/c空间群,晶胞参数为a=1.178 5(6)nm,b=0.542 5(3)nm,c=0.966 5(5)nm,β=126.371(5)°,Z=8.在化合物中,Co2+离子与草酸基团沿b轴交替连接而形成一个1D直链结构,这些链状结构之间又通过氢键作用而形成一个3D的超分子化合物.
In the study,a novel cobalt oxalate compound,[Co（ C2O4）0. 5（ H2O） ]n（ 1） was synthesized. X-ray single crystal diffraction analysis results showed that the compound belongs to monoclinic,C2 /c space group with the cell parameters a = 1. 1785（ 6） nm,b = 0. 5425（ 3） nm,c = 0. 9665（ 5） nm,β = 126. 371（ 5） °,Z = 8. Each Co2 ＋cations was coordinated with four oxygen atoms from two oxalates and two oxygen atoms from two water molecules. The Co2 ＋cations and oxalate anions were alternately connected to form a 1D chain structure in the b axis direction,between which a 3D supramolecular compound was formed through hydrogen bond.
出处
《海南大学学报（自然科学版）》
CAS
2014年第3期225-228,232,共5页
Natural Science Journal of Hainan University
基金
国家自然科学基金(11204057)
海南省自然科学基金(112003
211010)
海南省教育厅项目(Hjkj2012-06)
海南大学青年基金项目(qnjy1237
qnjy1251)
关键词
配位聚合物
水热合成
草酸钴化合物
coordination polymers
hydrothermal synthesis
cobalt oxalate compound
