摘要
四唑类含能化合物具有氮含量高、密度高、热稳定性好、成气量大等优点。汇总和评述了N,N-二(1(2)氢-5-四唑基)胺及其非金属盐类化合物、金属配合物的合成、性能及应用研究进展。建议:(1)设计分子中有更多氮、氧原子和配位氧的化合物,以改善氧平衡、提高密度;(2)选制备容易、结构简单、性能优异的化合物为研究对象,开展该类化合物在钝感高能炸药、固体推进剂、火工品及新型气体发生剂等领域中的应用研究。
Tetrazole-based energetic materials have the advantages of high nitrogen content,high density,good thermal stability and large gas production. It summarized and reviewed the progresses of study about the synthesis,performance and application of N,N-bis（1（2）H-tetrazol-5-yl）amine（H2 BTA）and its nonmetallic salt compounds and metallic complexes. It suggested：（1）the compounds aiming at more nitrogen,oxygen atoms and coordinated oxygen within molecule are designed to improve the oxygen balance and improve the density.（2）choosing the compounds with easy preparation,simple structure and excellent performance as research target,or the application research of in the field of insensitive high energy explosives,solid propellants,initiating explosive device and novel gas generating agent.
出处
《含能材料》
EI
CAS
CSCD
北大核心
2014年第5期709-715,共7页
Chinese Journal of Energetic Materials
基金
总装十二五预研项目(51328040304)
关键词
有机化学
四唑类含能化合物
合成
性能
进展
organic chemistry
tetrazole-based energetic materials
preparation
property
