摘要
The intramolecular electronic communication and multilevel ion-pairing effect of triferrocenylmethane（TriFcM） in organic phase was studied with the ＂thin-layer electrochemistry＂ approach.Three pairs of symmetric peaks in cyclic voltammetry of TriFcM correspond to three one-electron electrochemical reaction processes and indicate strong intramolecular electronic communication,which could be used to study the multilevel ion-pairing effect.Three different formation constants of ion-pairs between the three ferroceniums of TriFcM and perchlorate in thin organic film were obtained and compared.
The intramolecular electronic communication and multilevel ion-pairing effect of triferrocenylmethane（TriFcM） in organic phase was studied with the ＂thin-layer electrochemistry＂ approach.Three pairs of symmetric peaks in cyclic voltammetry of TriFcM correspond to three one-electron electrochemical reaction processes and indicate strong intramolecular electronic communication,which could be used to study the multilevel ion-pairing effect.Three different formation constants of ion-pairs between the three ferroceniums of TriFcM and perchlorate in thin organic film were obtained and compared.
基金
the NSFC(No.21173023)
the 111 Project(No.B07012) in China and the TriFcM provided from professor Hua-Zhong Yu at Simon Fraser University in Canada
