摘要
1,3,4-噁二唑类化合物因具有独特的生物活性和光电性能而被广泛研究,在医药、有机电子和发光材料等领域具有广泛的应用价值.引入多个1,3,4-噁二唑结构单元,常常可以进一步提高此类化合物的功效性.通过将苯甲醛类化合物上的醛基转化为氰基后,再转化为四唑基,然后由苯四唑类化合物和对甲酰基苯甲酰氯反应生成1,3,4-噁二唑类化合物,此化合物保留了对甲酰基苯甲酰氯带入的醛基,可以进一步地采用相同方法循环反应下去,从而可以得到含有多个1,3,4-噁二唑-苯结构单元的系列链状化合物.
Due to particular bioactivities and photoelectric properties, organic compounds containing 1,3,4 -oxadi- azole have been widely investigated and applied in many fields, such as pharmaceutics, organic electronics and lu- minescent materials. The performances of these compounds usually would be improved by introducing multiple 1,3, 4- oxadiazole groups. In this paper, a series of chain compounds composed of cyclical 1,3,4 -oxadiazole -ben- zene units were synthesized through the aldehyde group on benzene ring being transformed successively into the cya- no and 1 H - tetrazole group, and then reacting with 4 - formylbenzoyl chloride. Such reactions can he recycled continuously due to a new aldehyde group on benzene ring being introduced in the resultant compounds deriving from 4 - formylbenzoyl chloride.
出处
《云南民族大学学报（自然科学版）》
CAS
2014年第6期411-414,共4页
Journal of Yunnan Minzu University:Natural Sciences Edition
基金
国家自然科学基金(21262046)
云南省教育厅理工重点项目(2011Z003)
云南民族大学青年基金(11QN05)
关键词
1
3
4-噁二唑
链状化合物
苯甲腈
苯四唑
对甲酰基苯甲酰氯
1,3,4 - oxadiazole
chain compound
benzonitrile
5 - phenyl - 1H - tetrazole
4 - formylbenzoyl chloride
