摘要
成功合成了含咪唑环不对称双季铵盐,通过失重法、电化学阻抗谱、动电位扫描极化曲线、扫描电镜对合成产物在3%Na Cl的饱和二氧化碳溶液中的缓蚀效率进行研究。结果表明,其在饱和二氧化碳溶液中对钢铁有着良好的缓蚀作用,缓蚀效率接近90%;运用Langmuir吸附等温式对吸附行为进行了拟合,表明其吸附类型符合Langmuir吸附模型,吸附方式为化学吸附。
The asymmetric bis quaternary ammonium salt containing imidazole ring was synthesised suc-cessfully. And weight-loss method,electrochemical impedance spectroscopy,potentiodynamic polarization curve,scanning electron microscopy was used to study on the inhibition efficiency of this product in sodi-um chloride solutions(3. 00%)bubbled with CO2-saturated. The result shows that it has good corrosion inhibition for the P110 steel in this solution,and the corrosion inhibition efficiency is closed to 90%. The adsorption behavior was fitted using the Langmuir adsorption isotherm,and showed that the adsorption type conforms to the Langmuir adsorption isotherm,its adsorption mode is chemical adsorption.
出处
《应用化工》
CAS
CSCD
2014年第12期2217-2221,2224,共6页
Applied Chemical Industry
基金
四川省科技厅2013年应用基础研究计划(2013JY)
关键词
缓蚀剂
电化学测试
扫描电镜
缓蚀性能
吸附类型
corrosion inhibitor
electrochemical measurement
SEM
corrosion inhibition performance
adsorption type