摘要
为了改进钒基固溶体贮氢材料的性能,采用超声搅拌辅助铸造法制备新型钒基固溶体贮氢材料V3Ti Ni0.56Co0.1Al0.2,并进行物相组成、显微组织、吸放氢性能和耐腐蚀性能的测试与分析。结果表明,该新型钒基固溶体贮氢材料由V基固溶体相和少量的Ti Ni相、Ti2Ni相组成,具有较佳吸放氢性能和耐腐蚀性能,室温最大吸氢量为1.781%、室温放氢平台压力为0.46 MPa,腐蚀电位较V3Ti Ni0.56正移709 m V。
In order to improve the properties of V-based solid solution hydrogen storage materials,ultrasonic stirring assisted casting method was used to prepare a new V-based solid solution hydrogen storage material V3 Ti Ni0.56Co0.1Al0.2.The phase compositions,microstructure,hydrogen absorption and desorption properties and corrosion resistance of the material were tested and analyzed.The results show that the new material consists of V-based solid solution phase,small amount of Ti Ni and Ti2 Ni phases,and it has favorable hydrogen absorption and desorption properties and corrosion resistance,of which the maximum hydrogen absorption capacity at room temperature is 1.781% and the plateau pressure of hydrogen desorption at room temperature is 0.46 MPa,and the corrosion potential shifts positively by 709 m V in comparison to V3 Ti Ni0.56.
出处
《钢铁钒钛》
CAS
北大核心
2014年第5期21-24,共4页
Iron Steel Vanadium Titanium
基金
吉林省教育厅科研基金项目(99 10)
关键词
钒基固溶体贮氢材料
V3Ti
Ni0.56Co0.1Al0.2
超声搅拌
吸放氢
耐腐蚀
V-based solid solution hydrogen storage materials
V3Ti Ni0.56Co0.1Al0.2
ultrasonic stirring
hydrogen absorption and desorption
corrosion resistance