摘要
以二茂铁甲酸为原料,经氯代和酰胺化反应合成了两个新型的二茂铁甲酰胺衍生物——N-苯基二茂铁甲酰胺(4a)和N-4-甲苯基二茂铁甲酰胺(4b),其结构经1H NMR,IR和MS表征。利用循环伏安法研究了4a和4b的电化学性质。结果表明,扫描速率为10 m V·s-1时,4a和4b分别在1.2 V^-0.05 V和0.8 V^-0.4 V出现一对氧化还原峰,ΔEp分别为0.09 V和0.05 V,ipc/ipa≈1。
Two novel ferrocene formamide derivatives,N-phenyl ferrocene formamide（4a） and N-4-tolyl ferrocene formamide（4b）,were synthesized by chlorination and amidation reaction from ferrocenecarboxylic acid. The structures were characterized by1 H NMR,IR and MS. The electrochemical properties of 4 were investigated by cyclic voltammetry. The results showed that when the scanning rate was 10 m V·s^- 1,ΔEpof 4a and 4b were 0. 09 V and 0. 05 V,respectively,and ipc/ ipa≈1.
出处
《合成化学》
CAS
CSCD
2015年第2期134-136,共3页
Chinese Journal of Synthetic Chemistry
基金
辽宁省自然科学基金资助项目(2013020085)
关键词
二茂铁甲酰胺
合成
电化学性质
ferrocene formamide
synthesis
electrochemical property
