摘要
Petroleum sulfonate is one of the most important surfactants used in surfactant flooding for enhanced oil recovery, which is mainly obtained by treating high-boiling petroleum fractions in a stirred tank reactor(STR) or in a fallingfilm reactor(FFR). The synthesis of petroleum sulfonate with ultra-low interfacial tension from viscous petroleum fractions was carried out in a rotating packed bed(RPB) reactor using dilute liquid sulfur trioxide as the sulfonating agent in this study. The effects of various experimental conditions on components content and oil-water interfacial tension(IFT) were investigated. Under the optimum conditions, the active matter content could reach up to 50.3% and the IFT could be equal to 4.7×10-3 m N/m. Compared with the traditional reactor, the active matter content is by 14.12% higher in the RPB as compared to that obtained in the STR. The uneven change of the test oil droplets during the IFT measurement was also discussed. The increase of heavy components content not only can eliminate the contraction phenomenon, but also can reduce the IFT to a minimum. This can be conducive to explaining the reason for producing IFT and the preparation of proper formulations for practical application.
Petroleum sulfonate is one of the most important surfactants used in surfactant flooding for enhanced oil recovery,which is mainly obtained by treating high-boiling petroleum fractions in a stirred tank reactor （STR） or in a fallingfilmreactor （FFR）. The synthesis of petroleum sulfonate with ultra-low interfacial tension from viscous petroleum fractionswas carried out in a rotating packed bed （RPB） reactor using dilute liquid sulfur trioxide as the sulfonating agent in thisstudy. The effects of various experimental conditions on components content and oil-water interfacial tension （IFT） wereinvestigated. Under the optimum conditions, the active matter content could reach up to 50.3% and the IFT could be equalto 4.7×10？3 mN/m. Compared with the traditional reactor, the active matter content is by 14.12% higher in the RPB ascompared to that obtained in the STR. The uneven change of the test oil droplets during the IFT measurement was also discussed.The increase of heavy components content not only can eliminate the contraction phenomenon, but also can reducethe IFT to a minimum. This can be conducive to explaining the reason for producing IFT and the preparation of proper formulationsfor practical application.
基金
supported by Project of the National Twelfth Five-Year Research Program of China (Grants. 2014BAE03B02)
