摘要
卟啉及其金属配合物由于其结构的易修饰性和性质的可调控性成为常用的超分子骨架。从卟啉环合方法和卟啉取代基修饰两个方面综述了卟啉及其衍生物的合成研究进展;以卟啉经典合成方法为基础,介绍了各类复杂结构卟啉的合成条件及适用范围。
Porphyrins and metalloporphyrins are widely used as supramolecular scaffold due to the flexibility of structures and adjustability of properties. Research progress of synthesis of porphyrins and their derivatives are reviewed from two parts:eyclization of porphyrin, substituent group modification of porphyrin. Based on tra- ditional synthesis of porphyrin, the synthetic conditions and application scope of porphyrin with complex struc- ture are introduced.
出处
《化学与生物工程》
CAS
2015年第4期15-20,共6页
Chemistry & Bioengineering
关键词
卟啉
金属卟啉
合成
环合
修饰
porphyrin
metalloporphyrin
synthesis
cyclization
modification