摘要
A novel ferruginous active absorbent, prepared by fly ash, industrial lime and the additive Fe（VI）, was introduced for synchronous abatement of binary mixtures of SO2–NOx from simulated coal-fired flue gas. The synergistic action of various factors on the absorption of SO2 and NOx was investigated. The results show that a strong synergistic effect exists between Fe（VI） dose and reaction temperature for the desulfurization. It was observed that in the denitration process, the synergy of Fe（VI） dose and Ca/（S ＋ N） had the most significant impact on the removal of NO, followed by the synergy of Fe（VI） and reaction temperature, and then the synergy of reaction temperature and flue gas humidity. A scanning electron microscope（SEM） and an accessory X-ray energy spectrometer（EDS）were used to observe the surface characteristics of the raw and spent absorbent as well as fly ash. A reaction mechanism was proposed based on chemical analysis of sulfur and nitrogen species concentrations in the spent absorbent. The Gibbs free energy, equilibrium constants and partial pressures of the SO2–NOx binary system were determined by thermodynamics.
A novel ferruginous active absorbent, prepared by fly ash, industrial lime and the additive Fe（VI）, was introduced for synchronous abatement of binary mixtures of SO2–NOx from simulated coal-fired flue gas. The synergistic action of various factors on the absorption of SO2 and NOx was investigated. The results show that a strong synergistic effect exists between Fe（VI） dose and reaction temperature for the desulfurization. It was observed that in the denitration process, the synergy of Fe（VI） dose and Ca/（S ＋ N） had the most significant impact on the removal of NO, followed by the synergy of Fe（VI） and reaction temperature, and then the synergy of reaction temperature and flue gas humidity. A scanning electron microscope（SEM） and an accessory X-ray energy spectrometer（EDS）were used to observe the surface characteristics of the raw and spent absorbent as well as fly ash. A reaction mechanism was proposed based on chemical analysis of sulfur and nitrogen species concentrations in the spent absorbent. The Gibbs free energy, equilibrium constants and partial pressures of the SO2–NOx binary system were determined by thermodynamics.
基金
supported by the National Natural Science Foundation of China (Nos. 51308212, 10974053)
the National Key Technology R&D Program (No. 2011BAI02B03)
the Fundamental Research Funds for the Central Universities (No. 13ZD18)
the State Scholarship Fund (No. 201206735009)
