摘要
在水热条件下合成了配位聚合物:[Zn(BIX)2Cl2]n(BIX=1,4-bis(imidazol-1-methyl)phenyl),并通元素分析和单晶X-射线衍射对其进行了表征.结构表明该化合物属于单斜晶系:空间群P2(1)/c,晶胞参数a=15.398(8),b=20.194(11),c=20.436(11),β=91.594(1)°,V=5 992.99(60)3,Dc=1.566 68 g/cm3,C14H14N4Zn Cl2,Mr=374.602 3,F(000)=3 040.0,Z=4.00,GOOF=0.884,R1=0.0448,wR2=0.1229.该化合物表现出S型链状结构,并且两条链通过氢键的作用形成相互垂直缠绕的柔性长链结构.
The coordination polymers synthesized under hydrothermal conditions[Zn（BIX）2Cl2]n（BIX = 1,4 -bis（ imidazol-1 - methyl ） phenyl ）,and were characterized by elemental analysis and single crystal X-ray diffraction. The structure showed that the compound belongs to the triclinic space group P2（1）/c,the unit cell parameters a=15. 398（8）°,b=20. 194（11）°,c=20. 436（11）°,β=91. 594（1）°,V=5 992. 99（60）°3 ,Dc=1. 566 68 g/cm3,C14 H14 N4ZnCl2,Mr =374. 602 3,F（000）=3 040. 0,Z =4. 00,GOOF =0. 884,R1 =0. 0448 ,wR2=0 . 122 9 . It exhibits the S word chain structure ,and the two chains formed a the mutual vertical winding structure of flexible long chain through hydrogen bonds.
出处
《吉林师范大学学报（自然科学版）》
2015年第2期95-98,共4页
Journal of Jilin Normal University:Natural Science Edition
基金
吉林省科技发展计划项目(20140204080GX)
关键词
水热合成
晶体结构
配位聚合物
hydrothermal synthesis
crystal structure
coordination ploymer
