期刊文献+

紫外消解流动注射分光光度法测定地表水中总氮的实验研究

Determination of Total Nitrogen in Water by Ultraviolet Digestion and Flow Injection Spectrophotometry
下载PDF
导出
摘要 应用荷兰Skalar公司的SAN++连续流动注射分析仪测定地表水中的总氮,建立测定地表水中总氮的流动注射分析法。结果显示该方法分析速度快,分析速率可达32个/小时,仪器测定浓度与峰高响应值相关性很高,相关系数为0.999 6,线性范围0.0 mg/L^5.00 mg/L,方法检出限为0.03 mg/L,精密度RSD小于4%,均满足国家实验质量标准要求。紫外消解流动注射分光光度法测定地表水总氮具有分析速度快、准确度高、干扰少,适合大批量的地表水分析。 This study uses SAN ++ continuous flow injector manufactured by Skalar to determine total nitrogen in surface wa- ter, The results show that the method is fast 32 samples could be tested per hour. This method had a high correlation between con- centration and peak height. The correlation coefficient is 0. 9996, the linear range is 0 -5 mg/L, the detection limit was 0. 03 mg/L, and the precision of RSD is less than 4%. These results meet the national standards for the quality requirements. This method has the advantages of quick analysis speed, high accuracy, less interference, which is suitable for large quantities of surface water analysis.
作者 贺亮 高欣
出处 《环境科学与管理》 CAS 2015年第5期127-130,共4页 Environmental Science and Management
关键词 流动注射分析 地表水 总氮 flow injection surface water total nitrogen
  • 相关文献

参考文献6

二级参考文献13

  • 1刘燕,申志林.水质总氮空白实验的分析及改进措施[J].环境科学与技术,2005,28(B06):46-48. 被引量:11
  • 2齐文启,孙宗光,陈伟军,邹子川,黄平柱,严尚华,董玉珍.水中的总磷及其自动在线监测仪的研制[J].现代科学仪器,2005,22(5):23-31. 被引量:6
  • 3国家环境保护总局水和废水监测分析方法编委会.水和废水监测分析方法[M].第四版.北京:中国环境科学出版,2002:784.
  • 4Ruzicka J, Hansen E H. Flow injection analysis[M]. 2nd ed. New York:John Wiley and Sons, 1988.
  • 5Diniz M C T, Flho O F, Aquino E V, et al. Determination of phosphate in natural water employing a monosegmented flow system with simultaneous multiple injection[J]. Talanta, 2004,62(3) :469-475.
  • 6Motomizu S, Li Z H. Trace and ultratrace analysis methods for the determination of phosphorus by flow-injection techniques[J]. Talanta, 2005,66(2 ): 332-340.
  • 7Legnerova Z,Solich P,Sklena?ova H,et al.Automated simultaneous monitoring of nitrate and nitrite in surface water by sequential injection analysis[J].Water Res,2002,36 ( 11 ) : 2777-2783.
  • 8国家环境保护总局水和废水监测分析方法编委会.水和废水监测分析方法(第四版)[M].北京:中国环境科学出版社,2002.32-37.
  • 9Mason C. J., Coe G., Edwards M. et al, The use of microwaves in the acceleration of digestion and colour development in the determination of total Kjeldahl nitrogen in soil[ J ]. Analyst, 1999,124 : 1719.
  • 10Kokot S, King G, Keller H. R. et al, Microwave digestion: an analysis of procedures [ J]. Anal. Chim. Acta 1992, 259:267.

共引文献12

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部