摘要
负载型氮杂环卡宾钯催化的C—C偶联反应由于具有反应活性高,催化剂便于分离和可重复使用等特点,已引起了人们的广泛关注.负载型氮杂环卡宾钯催化剂中的载体材料对催化性能和重复使用性能具有较大的影响.综述了不同类型载体材料制备的负载型氮杂环卡宾钯催化C—C偶联反应的研究进展,载体类型包括聚合物材料、硅材料、碳材料和磁性纳米粒子材料.此外,还对负载型氮杂环卡宾钯催化剂未来的发展前景进行了展望.
The C-C coupling reactions catalyzed by supported N-heterocyclic carbene palladium complex have attracted considerable attention because catalytic activity is excellent and supported catalyst can be separated easily and reused several times. The performance of the carriers has an important effect on the catalytic activity and reusability of the supported catalyst. In this paper, the advances in the C-C coupling reactions catalyzed by supported N-eterocyclic carbene palladium complex have been reviewed. Polymer, silica, carbon and magnetic nanoparticles were used to support the N-heterocyclic carbene palladium catalysts. Finally, the direction of the supported N-heterocyclic carbene palladium complex was also put forward.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2015年第5期961-974,共14页
Chinese Journal of Organic Chemistry
基金
江西省自然科学基金(No.20114BAB213011)
江西省教育厅基金(No.GJJ13447)
核资源与环境重点实验室(东华理工大学)开放基金(No.NRE1315)
东华理工大学博士科研启动基金(No.DHBK1010)
核资源与环境省部共建国家重点实验室培育基地(东华理工大学)开放基金(No.NRE1315)
国家自然科学基金(No.31101469)
新世纪优秀人才支持计划(No.NCET-12-0475)
陕西省青年科技新星(No.2012KJXX-16)
中央高校基本科研业务费(No.QN2011035)资助项目~~
关键词
C—C偶联反应
氮杂环卡宾
负载型催化剂
钯催化
C-C coupling reaction
N-heterocyclic carbene
supported catalyst
palladium catalysis
