期刊文献+

纳米ZnO改性不饱和聚酯树脂的研究 被引量:3

Study on Unsaturated Polyester Resin Modified by Nano-ZnO
下载PDF
导出
摘要 采用纳米ZnO(nano-ZnO)对不饱和聚酯树脂(UPR)进行改性,研究nano-ZnO添加量对nano-ZnO/UPR复合体系综合性能的影响。结果表明:nano-ZnO对UPR具有明显的增强增韧作用,随着nano-ZnO添加量的增加,nano-ZnO/UPR复合体系的黏度和凝胶时间随之增大,拉伸强度、弯曲强度和冲击强度均呈先增大后减小的趋势,吸水率呈先减小后增大趋势,当添加量为5%时,nano-ZnO/UPR复合体系的综合性能最好,固化反应的表观活化能(E)为51.6 k J/mol,反应级数(n)为0.892。 Unsaturated polyester resin (UPR) was modified by nano-ZnO, and the effect of nano-ZnO addi- tion on the comprehensive properties of the nano-ZnO/UPR composite system was studied. The results show that the nano-ZnO has an obvious reinforcing and toughening effect on the UPR. With the increase of the nano-ZnO additive amount, the viscosity and gel time of the nano-ZnO/UPR composite system increase, the tensile strength, flexural strength, and impact strength increase at first and then decrease, and the water absorption decreases first and then increases. When the additive amount of nano-ZnO is 5%, the comprehensive properties of the nano-ZnO/UPR composite system are the best, the apparent activation energy(E) of curing reaction is 51.55 kJ/mol, and the reaction order(n) is 0.892.
出处 《绝缘材料》 CAS 北大核心 2015年第6期21-24,29,共5页 Insulating Materials
基金 广州市科技计划项目(20134400217)
关键词 纳米ZNO 不饱和聚酯树脂 改性 nano-ZnO unsaturated polyester resin modify
  • 相关文献

参考文献17

  • 1魏珂瑶,周莉,张建中,张林.无机纳米粒子-不饱和聚酯树脂复合材料的研究进展[J].化学与粘合,2012,34(6):58-60. 被引量:2
  • 2李毅,唐安斌,黄杰,马寒冰.磷腈改性不饱和聚酯树脂的阻燃及耐热性能研究[J].绝缘材料,2014,47(4):33-36. 被引量:8
  • 3卢凤英,吕建,胡舒龙,章震,刘华山,曾德明.SBA-15/不饱和聚酯树脂的制备及其性能研究[J].绝缘材料,2014,47(2):41-44. 被引量:2
  • 4Chirayil C J, Mathew L, Hassan P A, et al. Rheological Be- haviour of Nanocellulose Reinforced Unsaturated Polyester Nanocomposites[J]. International Journal of Biological Macro- molecules,2014,69:274-281.
  • 5Chirayil C J, Joy J, Mathew L, et al. Nanofibril Reinforced Unsaturated Polyester Nanocomposites:Morphology, Mechani- cal and Barrier Properties, Viscoelastic Behavior and Poly- mer Chain Confinemant[J]. Industrial Crops and Products, 2014,56:246-254.
  • 6Kayatin M J, Davis V A. Viscoelasticity and Shear Stability of Single-walled Carbon Nanotube/Unsaturated Polyester Res- in Dispersions[J]. Macromolecules,2009,42(17):6624-6632.
  • 7Albdiry M T, Ku H, Yousif B F. Impact Fracture Behav- iour of Silane-treated Halloysite Nanotubes-reinforced Unsatu- rated Polyester[J]. Engineering Failure Analysis,2013,35:718- 725.
  • 8Albdiry M T, Yousif B F. Morphological Structures and Tri- bological Performance of Unsaturated Polyester Based Un- trcatcd/Silane-treated Halloysite Nanotubes[J]. Materials & Design,2013,48:68-76.
  • 9Esfahani J M, Sabet A R, Esfandeh M. Assessment of Nano- composites Based on Unsaturated Polyester Resin/Nanoclay under Impact Loading]J]. Polymers for Advanced Technolo- gies,2012,23(4):817-824.
  • 10Kaffashi B, Honarvar F M. The Effect of Nanoclay and MWNT on Fire-retardency and Mechanical Properties of Unsaturated Polyester Rasins[J]. Journal of Applied Poly- mer Science,2012,124(2):1154-I 159.

二级参考文献62

共引文献40

同被引文献30

  • 1Li G, Jiang J M, Jin J H, et al. CrystallizationBehavior of Modified Polyester with Varied Macromolecular Architec ture[J]. Journal of Macromolecular Science, Part B: Physics, 2006, 45: 639-652.
  • 2Syang-peng R. Properties of Poly(ethylene terephthalate)/ Poly(ethylene naphthalate) Blends[J]. Polymer Enginee- ring and Science, 1999, 39(12): 2475 -2481.
  • 3Bikiaris D N, Karayannidis G P. Synthesis and Characteri- sation of Branched and Partially Crosslinked Poly(ethylene terephthalate) [J]. Polymer International, 2003, 52: 1230-1239.
  • 4Tracey L H , John S F , David S , et al. CrystallisationKinetics of Novel Branched Poly(ethylene terephthalate) : a Small-angle X-ray Scattering Study[J]. Polymer Interna- tional, 2006, 55: 1435-1443.
  • 5Li G, Yang S L, Jiang J M, et al. Crystallization Charac- teristics of Weakly Branched Poly(ethylene terephthalate) [J]. Polymer, 2005, 46: 11142-11148.
  • 6Seung B K, Yannick A, Yves L, et al. Rheological Pro- perties of Hyperbranched Polymer/Poly (ethylene tereph- thalate) Reactive Blends[J]. Polymer Engineering and Sci- ence, 2003, 43(2): 329-343.
  • 7Hess C, Hirt P, Oppermann W. Influence of Branching on the Properties of Poly(ethylene terephthalate) Fibers [J]. Journal of Applied Polymer Science, 1999, 74: 728-734.
  • 8Li G, Yang S L, Jiang J M, et al. The Complicated In- fluence of Branching on Crystallization Behavior of Poly (ethylene terephthalate)[J]. Journal of Applied Polymer Science, 2008, 110: 1649-1655.
  • 9Ruxandra F Rosu, Robert A Shanks, Sati N Bhatta- charya. Synthesis and Characterisation of Branched Poly (ethylene terephthalate) [J]. Polymer International, 1997, 42(3): 267-275.
  • 10Supaphol P, Dangseeyun N, Srimoaon P, et al. Noniso- thermal Melt-Crystallization Kinetics for Three Linear Aromatic Polyesters [J]. Thermochimica Acta, 2003, 406:207- 220.

引证文献3

二级引证文献4

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部