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不同联接基的烷基咪唑表面活性剂的合成与表征 被引量:1

Synthesis and Characterization of Alkyl Imiazole Surfactant with Different Spacer
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摘要 以咪唑和溴代十二烷为原料、1,2-二溴乙烷(1,4-二溴丁烷、对二溴苄)为联接基团,经两步反应合成标题化合物。利用IR、1HNMR对目标产物进行结构表征,并测定了目标产物的CMC、润湿性和泡沫稳定性。结果表明,合成的表面活性剂具有较低的CMC值,不同联接基团对CMC值影响不大,柔性联接基团的表面活性剂具有较好的润湿性和泡沫稳定性。 Alkyl imidazole surfactants with different spacer were synthesized via two steps with imidazole,bromododecane and 1,2-dibromethane( 1,4-dibromo-butane,dibromo-p-xylene) as raw material. The structures were confirmed by IR and1 HNMR. The CMC value,wettability and foam stability of the target products were tested. Results show that the synthesized of alkyl imidazole surfactants have low CMC values. The effect of different spacer on CMC values is not obvious. Alkyl imidazole surfactants with the flexible spacer have better wettability and foam stability.
出处 《化学试剂》 CAS 北大核心 2015年第9期848-850,共3页 Chemical Reagents
基金 黑龙江省教育厅科学技术研究基金资助项目(12541864)
关键词 不同联接基 烷基咪唑表面活性剂 合成 different spacer alkyl imiazole surfactant synthesis
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参考文献7

  • 1MENGER F M ,LITTAU C A. Gemini surfactants :synthe- sis and properties[J]. J. Am. Chem. Soc. ,1991,113(4) : 1 451-1 452.
  • 2MENGER F M. Gemini surfactants [J]. Angew. Chem. Int. Ed. ,2000,39(11) :1 906-1 920.
  • 3ERHARDT R,BOKER A,ZETTL H. Janus micelles[J]. Macromolecules, 2001 , 34 ( 1 ) : 1 069-1 075.
  • 4MUZZALUPO R, GENTE G. Micelles in mixtures of sodi- um dodccyl sulfate and a bola-form surfactant[J]. Lang- muir,2006,22(14) :6 001-6 009.
  • 5ACHOURI M E, INFANTE M R. Some cationic gemini surfactants and their inhibitive effect on iron corrosion in hydrochloric acid[J]. Corros. Sci. , 2001,43 ( 1 ) : 19-35.
  • 6王丽艳,霍世超,佟白,赵冰,孙竹,孙雷.含羟基连接基的咪唑双子表面活性剂的合成研究[J].印染助剂,2014,31(7):16-19. 被引量:3
  • 7张华.现代有机波谱分析[M].北京:化学工业出版社,2007:68-86.

二级参考文献13

  • 1VICTORIA G,SANCHE Z,CLAUDIO J,et a/.Synthesis, surface-ac- tive properties, and anthelmintic activities of new cationic Gemini surfactants against the gastrointestinal nematode, heligmosomoides polygyrus bakeri, in vitro[J].J. Surfact. Deterg.,2012,15(4):463-470.
  • 2MENGER F M,LITTAU C A.Gemini suffactants: synthesis and prop- erties[J].J. Am. Chem. Soc.,1991,113(4):1 451-1 452.
  • 3ZANA R,BENRRAOU M,RUEFF R.Effeet of the spacer chain length on the critical mieelle concentration and micelle ionization degree[J]. Langmuir,1991,7(6):1072-1 075.
  • 4MARC P,MATHIAS H,CHRISTIAN F.Mechanism of Gemini disul- fide detergent mediated oxidative refolding of lysozyme in a new arti- ficial chaperone system[J].Protein J.,2010,29(7):457-465.
  • 5NORAHM M,DAWID J J,KI,UMPERMAN B.Application of Gemini surfactants as diesel fuel wax dispersanls[J].Energy Fuels 2011,25(1): 162-171.
  • 6LAI C C,CHEN K M.Deing properties of modified Gemini surfac- rants on a disperse dye-polyester system[J].Text. Res. J.,2008,78(5): 382-389.
  • 7LIOR Z,HFE Y I,,SR1NIVASA R.Unraveling the mechanism of nano- tube formation by chiral self-assembly of amF, hiphiles[J].J. Am. Chem. Soc.,2011,133(8):2 511-2 517.
  • 8CHANC W G,SHEN Y H,XIE A J.Controlled synthesis of CdSe and CdSe/CdS ere/shell nanopartic'les using Gemini surfaetant Py- 16-10 -16 and their bir'onjugates with BSA[J].J. Colloid Interface Sci.,2009, 335(2):257-263.
  • 9BELONG K K.KYUNG 0 D,YUN U B.Synthesis and optimization ofcholesterol- based diquaternary ammonium Gemini surfactant (Chol- GS) as a new gene delivery vector[J].J. Microbiol. Biotechnol.,2011, 21(1):93-99.
  • 10COLOMER A,P1NAZO A,MANRESA M A.Cationic surfaelanls de- rived from l-lysine: effects of their structure and charge type on anti- microbial and hemolytic activities[J].J. Med. Chem.,2011,54(4): 989-1 002.

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