期刊文献+

二元溶液凝固过程中组分通量随时间演化的实验研究

Experimental investigation of time-dependent compositional flux in solidifying binary aqueous solutions
原文传递
导出
摘要 该文在氯化铵水溶液定向凝固过程中,观察液相区双扩散对流条纹的形成并研究其随时演化规律。在固液混合边界层中,由于固态氯化铵盐的析出形成由盐度梯度驱动的多孔杂质模式下的对流运动。其中形成的低温、低浓度的柱状羽流与液态区进行热盐交换,导致了双扩散对流条纹的形成和移动。通过平行光暗影法成像,系统地分析了双扩散对流条纹移动速度的演化过程,由此确定了二元溶液凝固过程中由凝固区向液态区提供的盐流体积通量随时函数关系。结果表明,柱状羽流体积通量和时间成幂函数关系,幂指数为–1.51±0.18。而在某时刻,柱状羽流体积通量和高度成幂函数关系,幂指数约为2.5。同时,柱状羽流的卷吸率随溶液初始浓度的增加而减小,初始体积通量随初始溶液浓度的增加而减小。 The formation and evolution of double-diffusive layers (DDLs) in the liquid region are observed that occur during the directional solidification of aqueous ammonium chloride. Convection of porous media model driven by salinity gradient occurs due to the solidification in mushy layer. The cold and fresh chimney plumes transport heat and salt into the liquid region and thus the DDLs form and move. The downward propagating velocity of the DDLs is analyzed to determine the brine volume flux from mushy-layer convection. Results show that the brine volume flux decays as a power function of time with a power exponent of–1.51±0.18. Moreover, the brine volume flux increases as a power function of height, with a power exponent of about 2.5. As the initial concentration increases, the volume flux on mushy layer decreases and the entrainment rate decreases.
出处 《水动力学研究与进展(A辑)》 CSCD 北大核心 2015年第4期357-364,共8页 Chinese Journal of Hydrodynamics
基金 国家自然科学基金项目(11202151 11222222) 上海市浦江计划(13PJ1408800)~~
关键词 定向凝固 NH4Cl溶液 双扩散对流 多孔杂质模式对流 体积通量 unidirectional solidification aqueous ammonium chloride double-diffusive convection convection in porous media volume flux
  • 相关文献

参考文献31

  • 1WALSH J. The role of sea ice in climate variability: Theories and evidence[J]. Atmosphere-Ocean, 1983, 21(3): 229-242.
  • 2LAXON S, PEACOCK N, SMITH D. High interannual variability of sea ice thickness in the Arctic region[J]. Nature, 2003, 425(30): 947-950.
  • 3SERREZE M, HOLLAND M, STROEVE J. Perspecti- ves on the Arctic's Shrinking Sea-Ice Cover[J]. Science, 2007, 315: 1533-1536.
  • 4FELTHAM D,UNTERSTEINER N, WETTLAUFER J, et al. Sea ice is a mushy layer[J]. Geophysical Research Letters, 2006, 33: L14501.
  • 5HUPPERT H, WORSTER M. Dynamic solidification of a binary melt[J]. Nature, 1985, 314(25): 703-707.
  • 6HUPPERT H. The fluid mechanics of solidification[J]. Journal of Fluid Mechanics, 1990, 212: 209-240.
  • 7WORSTER M. Solidification of an alloy from a cooled boundary[J]. Journal of Fluid Mechanics, 1986, 167: 481-501.
  • 8WORSTER M. Natural convection in a mushy layer[J]. Journal of Fluid Mechanics, 1991, 224: 335-359.
  • 9TAIT S, JAUPART C. Compositional convection in viscous melts[J]. Nature, 1989, 338(13): 571-574.
  • 10CHEN F, LU J, YANG T. Convective instability in am- monium chloride solution directionally solidified from below[J]. Journal of Fluid Mechanics, 1994, 276: 163- 187.

二级参考文献15

  • 1CHIARELI A O P,WORSTER M G..On measurement and prediction of the solid fraction within mushy layers[J].J Crystal Growth,1992,125(3):487-494.
  • 2NISHIMURA T,IMOTO T,MIYASHITA H.Occurrence and development of double-diffusive convection during solidification of a binary system[J].Int J Heat Mass Transfer,1994,37(10):1455-1464.
  • 3WORSTER M G.Natural convection in a mushy layer[J].J Fluid Mech,1991,224(3):335-359.
  • 4CHEN C F,CHEN F.Experimental study of directional solidification of aqueous ammonium chloride solution[J].J Fluid Mech,1991,227(6):567-586.
  • 5CHANG M H,CHEN F.Stability characteristics of the mush affected by the solid layer below[J].J Crystal Growth,2003,255(4):369-378.
  • 6NISHIMURA T,SASAKI J,HTOO T T.The structure of plumes generated in the unidirectional solidification process for a binary system[J].Int J Heat Mass Transfer,2003,46(23):4489-4497.
  • 7HUPPERT H E,WORSTER M G.Measurement of the solid fraction in the crystallization of a binary melt[J].J Crystal Growth,1991,113(4):566-574.
  • 8Kaneko K, Koyaguchi T. Simultaneous crystallization and melting at both the roof and floor of crustal magma chambers: experimental study using NH4 Cl-H2O binary eutectic system [J]. J Volcanology Geothermal Res, 1999, 89(3/4) :303-315.
  • 9Wang S Y, Lin C X, Ebadian M A. Study of doublediffusive velocity during the solidification process using particle image velocimetry [J]. Int Journal of Heat and Mass Transfer, 1999, 42(24): 4427-4445.
  • 10Wang S Y, Lin C X, Ebadian M A. Vortex flow of low concentration NHa Cl-H2O solution during the solidification process [J]. Int Journal of Heat and Mass Transfer, 1999, 42(22) :4153-4163.

共引文献6

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部