摘要
以四元骨架镍（Ni-Al-Mo-Fe）为催化剂,脂肪族低碳硝基化合物经催化氢化还原反应合成了相应的氨基化合物。并探讨了其组成、粒径对催化氢化还原反应的影响。结果表明：100目-150目Ni-Al-Mo-Fe（Ni%〉90%）为最优组成,其催化氢化收率为95%,转化率均大于99%。
Aliphatic low-carbon nitro compounds were catalytic hydrogenated using four-element Raney Ni（ Ni-Al-Mo-Fe） as the catalyst. The effect of compostion and size of the catalyst to the hydrogenation was investigated. The results showed that 100 mesh - 150 mesh Ni-Al-Mo-Fe（ Ni% 90%） was the most suitable catalyst for the hydrogenation with the yields of 95%,and the conversion rates were more than 99%.
出处
《合成化学》
CAS
CSCD
2015年第10期960-962,共3页
Chinese Journal of Synthetic Chemistry
关键词
脂肪族低碳硝基化合物
四元骨架镍
催化氢化
合成
aliphatic low-carbon nitro compound
four-element Raney nickel
catalytic hydrogenation
synthesis
