期刊文献+

UV/PS和UV/H_2O_2工艺对水中甲氧苄氨嘧啶降解效果的对比研究 被引量:3

Comparison Study on Trimethoprim Degradation Efficiency by UV/H_2O_2 and UV/PS Processes in the Water
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摘要 对比了UV/PS(Persulfate,PS)和UV/H2O2工艺对甲氧苄氨嘧啶(Trimethoprim,TMP)的降解效果,考察了氧化剂浓度、TMP初始浓度、溶液p H值、水中共存阴离子和腐殖酸对降解效果的影响。实验结果表明,两种工艺都能有效去除水中低浓度的TMP,其降解速率都随氧化剂浓度的增加、目标污染物浓度的降低而增加;中性以及酸性条件有利于TMP的降解;水中共存阴离子对两种工艺降解TMP产生了不同的影响;腐殖酸对TMP的降解起明显的抑制作用。 UV/H2O2 and UV/PS have been used for the degradation of TMP in the water, and the degradation efficiencies were compared. Some affecting factors such as oxidant dosage, initial TMP concentrations, pH, coexisting anions and humic acid have also been investigated in this study. The result showed that both technologies could remove low concentrations of TMP in the water, the degradation rate increased as the initial TMP concentrations decreased and the oxidant dosage increased. The neutral or acidic conditions were favored for the degradation of TMP. The existing of anions had different effect on TMP degradation by the two technologies which slows down the TMP degradation to different degrees. The degradation performance was inhibited by humic acid obviously.
出处 《四川环境》 2015年第5期1-6,共6页 Sichuan Environment
基金 国家科技重大专项资助(2012ZX07403-001) 住房和城乡建设部研究开发项目(2009-K7-4)
关键词 UV/H2O2 UV/PS 甲氧苄氨嘧啶(TMP) 降解 UV/H2O2 UV/PS Trimethoprim degradation
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参考文献18

  • 1Oros-Ruiz S, Zanella R, Prado B. Photocatalytic degradation of trimethoprim by metallic nanoparticles supported on TiO < sub > 2-P25[ J]. Journal of hazardous materials, 2013, 263:28-35.
  • 2Siemens J, Huschek G, Siebe C, et al. Concentrations and mob- ility of human pharmaceuticals in the world's largest wastewater irrigation system, Mexico City-Mezquital Valley [ J ]. Water re- search, 2008, 42(8):2124-2134.
  • 3Homem V, Santos L. Degradation and removal methods of antibi- otics from aqueous matrices-A review [ J ]. Journal of Environ- mental Management, 2011, 92(10) :2304-2347.
  • 4李文书,李咏梅,顾国维.高级氧化技术在持久性有机污染物处理中的应用[J].工业水处理,2004,24(11):9-12. 被引量:29
  • 5Buxton G V, Bydder M, Salmon G A. The reactivity of chlorine atoms in aqueous solution Part II. The equilibrium SO4 + Cl- C1Nsbd + SO4^2- [ J]. Physical Chemistry Chemical Physics, 1999, 1 (2) :269-273.
  • 6Anipsitakis G P, Dionysiou D D. Transition metal/UV-based ad- vanced oxidation technologies for water decontamination[J]. Ap- plied Catalysis B : Environmental, 2004, 54 ( 3 ) : 155-163.
  • 7Crittenden J C, Hu S, Hand D W, et al. A kinetic model for H < sub > 2 O < sub > 2/UV process in a completely mixed batch reactor[ J]. Water research, 1999, 33 (10) :2315-2328.
  • 8Olmez-Hanci T, Arslan-Alaton I. Comparison of sulfate and hy- droxyl radical based advanced oxidation of phenol[ J ]. Chemical Engineering Journal, 2013, 224 : 10-16.
  • 9Daneshvar N, Behnajady M A, Mohammadi M, et al. UV/H < sub > 20 < sub > 2 treatment of Rhodamine B in aqueous solu- tion: Influence of operational parameters and kinetic modeling [J]. Desalination, 2008, 230( 1 ) :16-26.
  • 10Criquet J, Leitner N K V. Degradation of acetic acid with sulfate radical generated by persulfate ions photolysis [ J ]. Chemosphere, 2009, 77(2):194-200.

二级参考文献46

  • 1朱琨,王海涛,谢春娟,王恩鹏.UV-H_2O_2系统对水中2,4-二氯酚氧化降解研究[J].工业用水与废水,2006,37(1):27-31. 被引量:12
  • 2张志军,包志成,王克欧,郑明辉.二氧化钛催化下的氯代二苯并-对-二恶英光解反应[J].环境化学,1996,15(1):47-51. 被引量:51
  • 3潘晶,郝林,张阳,陈永强,索艳丽.溶液中阴离子和腐殖酸对UV/H_2O_2降解2,4-二氯酚的影响[J].环境污染与防治,2007,29(7):487-489. 被引量:16
  • 4[1]Huston Patrick L, et al. Degradation of selected pesticide active ingredients and commercial formulations in water by the photo-assited Fenton reaction [J ]. Wat. Res., 1999, 33 (5): 1 238 - 1 246
  • 5[2]Engwall Margaret A, et al. Degradation and detoxification of the wood preservatives creosote and pentachlorophenol in water by the photo-fenton reaction[J]. Wat. Res., 1999, 33(5): 1 151 - 1 158
  • 6[3]Pignatello J. Dark and photoassited Fe3+-catalyzed degradation of chlorophenoxy herbicides by hydrogen peroxide[J]. Environ Sci. Technol., 1992,26: 944 - 950
  • 7[4]Benitez F Javier, et al. Contribution of free radicals to chlorophenols decomposition by several advanced oxidation processes [J ]. Chemosphere, 2000, 41(8):1 271-1 277
  • 8[5]Vollmuth Stefan, et al. Degradation of PCDD, PCDF, PAH, PCB and Chlorinated Phenols During the Destruction-Treatment of Landfill Seepage Water in Laboratory Model Reactor (UV,Ozone, and UV/Ozone)[J]. Chemoshphere, 1995, 30(12):2 317-2 331
  • 9[7]Bandala Erick R, et al. Solar photocatalytic degradation of aldrin[J]. Catalysis Today, 2002,76(2): 189- 199
  • 10[8]Zaleska Adriana, et al. Photocatalytic degradation of lindane, p ,p'-DDT and methoxychlor in an aqueous environment [J]. Journal of Photochemistry and Photobiology A: Chemistry,2000, 135 (2 - 3):213-220

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