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Selective Mono-Ozonolysis of a Cyclic 1,5,9-Cyclododecatrien

Selective Mono-Ozonolysis of a Cyclic 1,5,9-Cyclododecatrien
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摘要 Some unsaturated compounds with the required (Z,Z)-double bonds configuration are synthesized through controlled ozonolysis process of 1,5,9-cyclododecatriene by determining the necessary amount of ozone passing through to selectively guarantee the breakage of a double bond while leaving other two bonds as (Z,Z). The products were diagnosed by using NMR spectrum, infrared (IR) and mass spectrometer techniques. It is concluded that these products could widely be used in the synthesis of insect pheromones instead of insecticides and as useful intermediate compounds in many chemical reactions.
出处 《Journal of Environmental Science and Engineering(A)》 2015年第9期474-483,共10页 环境科学与工程(A)
关键词 OZONOLYSIS cyclododecatriene ALKENES pheromone synthesis. 臭氧分解 不饱和化合物 循环 控制合成 双键结构 昆虫信息素 分解过程 核磁共振
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参考文献18

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