Selective Mono-Ozonolysis of a Cyclic 1,5,9-Cyclododecatrien
Selective Mono-Ozonolysis of a Cyclic 1,5,9-Cyclododecatrien
摘要
Some unsaturated compounds with the required (Z,Z)-double bonds configuration are synthesized through controlled ozonolysis process of 1,5,9-cyclododecatriene by determining the necessary amount of ozone passing through to selectively guarantee the breakage of a double bond while leaving other two bonds as (Z,Z). The products were diagnosed by using NMR spectrum, infrared (IR) and mass spectrometer techniques. It is concluded that these products could widely be used in the synthesis of insect pheromones instead of insecticides and as useful intermediate compounds in many chemical reactions.
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