摘要
用喷雾干燥法将GdPO4∶Tb纳米棒包裹在壳聚糖(CS)微球中,成功地制备了一种新颖的CS/GdPO4∶Tb复合物微球。利用X射线衍射仪(XRD)、傅立叶红外光谱仪(FT-IR)、场发射扫描电子显微镜(SEM)、透射电镜(TEM)等检测手段表征了产物的形貌和结构特征。分析表明,CS/GdPO4∶Tb微球呈鸟巢状,表面粗糙,其粒径约为5μm,其形貌与相同条件下得到的纯壳聚糖微球显著不同,这主要是由于GdPO4∶Tb纳米棒的骨架作用。磁性和荧光光谱的研究表明,该复合物同时具有良好的荧光性能和顺磁性,使其在生物医学领域具有潜在应用能力。
A novel bifunctional bioinorganic composite combined with the interesting properties of paramagnetism,fluorescence was successfully prepared by encapsulation of GdPO4∶Tb nanorods into the chitosan microsphere.The morphology and structure of the composite were characterized by X-ray diffraction(XRD),transmission electron microscope(TEM),scanning electron microscope(SEM),Fourier transform infrared spectrometer(FT-IR).The results showed that the CS/GdPO4∶Tb bifunctional microsphere owned nest-like shape and rough surface with an average diameter of 5μm,which is different from the pure chitosan.The formation process was preliminary discussed.Additionally,the photoluminescence spectra and the paramagnetic properties revealed that the as-prepared bifunctional composites exhibited efficient luminescence and paramagnetism that had potential in magnetic resonance and optical imaging.Our results suggested that the obtained functionalized microspheres might be very attractive for biomedical applications.
出处
《功能材料》
EI
CAS
CSCD
北大核心
2015年第21期21124-21127,21132,共5页
Journal of Functional Materials
基金
江西省教育厅资助项目(GJJ14578
GJJ13216)
江西省科技支撑资助项目(20142BBF60008)
大学生创新资助项目(20130704060)
