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稀土β-成核剂/玻璃纤维改性聚丙烯复合材料的制备及其性能研究 被引量:7

Preparation and Mechanical Properties of Rare Earth β-Nucleating Agent/Glass Fiber Modified Polypropylene Composites
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摘要 研究了不同含量稀土β-成核剂(WBG-Ⅱ)对玻璃纤维增强聚丙烯(GFRP)复合材料性能的影响。差示扫描量热仪(DSC)和X-射线衍射仪(XRD)的测试结果表明,材料的结晶度和结晶能力得到大幅提高,且晶体的形态由α-晶占主导变成β-晶占主导,玻璃纤维(GF)对β-成核剂有抑制作用。扫描电镜(SEM)结果表明,试样基体更加柔软,有利于提高冲击性能。当稀土β-成核剂添加量为0.10%时,试样的综合力学性能较优,其拉伸强度达到38.1 MPa,冲击强度8.7kJ/m^2。 Research on the influence of rare earth β-nucleating agent (WBG-II ) on the mechanical properties of glass fiber reinforced polypropylene composites (GFRP) was carried out. The results of differential scanning calorimetry (DSC) and X-ray diffraction (XRD) both showed that the crystallinity degree and crystallization ability were both greatly enhanced and the β-form PP was in the dominant position, GF depressed the activity of B-nucleating agent. Scanning electron microscope observation of the fracture surface of injection-molding GFRP also illustrates that the samples with rare earth B-nucleating agent are in favor of improving the impact strength and making the matrix softer. The sample with 0. 10% 13-nucleating agent in mass fraction possesses the best mechanical properties, of which the tensile strength and impact strength reach 38.1 MPa and 8.7 kJ/m^2, respectively.
出处 《塑料工业》 CAS CSCD 北大核心 2016年第4期106-110,共5页 China Plastics Industry
基金 上海市产学研合作项目(批准号:沪CXY-2014-023) 江苏省科技成果转化项目(批准号:SBA2014010034)
关键词 稀土β-成核剂 聚丙烯 玻璃纤维 Rare Earth Beta-nucleating Polypropylene Glass Fiber
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参考文献12

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