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全氟烷基磺酰亚胺配合物在均相与非均相催化反应中的应用 被引量：2

Review on the Application of Perfluoroalkylsulfonylimides Complexes in Homogeneous and Heterogeneous Catalysis
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摘要 普通的液体酸催化剂在应用过程中难免产生环境问题,而固体酸催化剂使用寿命短、活性低,全氟烷基磺酰亚胺配合物因其特殊的阴离子结构以及所具有的超酸性质而在新型催化领域表现出广泛的应用前景。文章介绍了全氟烷基磺酰亚胺配合物的结构与性能特点,综述了近年来全氟烷基磺酰亚胺配合物在催化领域的应用,重点阐述了在均相催化与多相催化反应中的最新进展,以期对其催化性能和应用前景有比较全面的认识。 Traditional liquid acid catalysts have environmental problems during their application, while solid acid catalysts have drawbacks for their low activity and short service life. Perfluoroalkylsulfonylimides complexes show a wide application in catalysis due to their special anionic structures and super acid properties.The structure and properties of perfluoroalkylsulfonylimides complexes are introduced in this review and their application as catalysts in homogeneous and heterogeneous catalysts are summarized. The development trends of perfluoroalkylsulfonylimides complexes are also discussed.
作者 詹晓力 唐永强 何逸波 张庆华 陈丰秋
机构地区 浙江大学化学工程与生物工程学院
出处 《高校化学工程学报》 EI CAS CSCD 北大核心 2016年第2期253-260,共8页 Journal of Chemical Engineering of Chinese Universities
基金 国家自然科学基金(UI362102)
关键词 全氟烷基磺酰亚胺 均相 非均相 催化 perfluoroalkylsulfonylimide homogeneous heterogeneous catalysis
分类号 TQ032.4 [化学工程]
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参考文献32

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二级参考文献56

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高校化学工程学报
2016年 第2期

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