期刊文献+

我国白酒蒸馏过程及原酒、成品酒中乙醛的研究 被引量:35

Research on acetaldehyde from distillation cut,raw liquor,finished liquor
下载PDF
导出
摘要 乙醛广泛存在于酒精饮料中,被国际癌症研究机构(IARC)确认为Ⅰ类致癌物(对人类致癌证据充分)。利用气相色谱-氢火焰离子化检测(GC-FID)技术检测我国馏分酒、原酒和成品白酒中乙醛,发现白酒固态蒸馏和液态二次蒸馏过程中乙醛和乙缩醛很快被馏出,含量较集中于前几个馏分,随着蒸馏进行,含量逐渐减少。原酒中乙醛质量浓度在45.10-763.93 mg/L,乙缩醛的质量浓度在61.50-2 871.52 mg/L,乙缩醛和乙醛的比例在2.26∶1-2.87∶1。成品白酒中乙醛质量浓度42.36-491.70 mg/L,乙缩醛的质量浓度在68.54-811.32 mg/L,乙缩醛和乙醛的比例在1.24∶1-1.96∶1,且成品白酒乙醛的平均质量浓度(173.24 mg/L)高于其他国家蒸馏酒中乙醛的质量浓度(≤86 mg/L)。我国成品白酒中乙醛的暴露边界(margin of exposure,MOE)值为622,因此白酒中乙醛对人类健康的潜在危害应给予较高关注。 Acetaldehyde,which widely exists in alcoholic beverages,is classified as group 1 carcinogen( sufficient evidence of carcinogenicity) by International Agency for Research on Cancer( IARC). In this paper,acetaldehyde from distillation cut,raw liquor,and Chinese finished liquor was quantified by gas chromatography-flame ionization detector( GCFID). During solid distillation process,acetaldehyde and acetal had higher values at the beginning of the distillation,but declined sharply along with the distillation process,which was similar to the second distillation of raw liquor. The acetaldehyde( 45. 10 - 763. 93 mg / L) and acetal concentrations( 61. 50 - 2 871. 52 mg / L) were detected in raw liquor,and the concentration ratio of acetaldehyde to acetal was 2. 26∶ 1 - 2. 87∶ 1. The acetaldehyde( 42. 36 - 491. 70 mg / L) and acetal concentrations( 68. 54 - 811. 32 mg / L) were detected in Chinese finished liquor,and the concentration ratio of acetaldehyde to acetal was1. 24∶ 1 - 1. 96∶ 1. The average concentration of acetaldehyde in Chinese finished liquor was 173. 24 mg /L,which was higher than that in other distilled spirit from different countries( ≤86 mg / L). The margin of exposure( MOE) was calculated to be 622 in Chinese finished liquor. Acetaldehyde in Chinese liquor should be of great concern.
出处 《食品与发酵工业》 CAS CSCD 北大核心 2016年第4期6-11,共6页 Food and Fermentation Industries
关键词 乙醛 乙缩醛 蒸馏 原酒 成品酒 暴露边界 acetaldehyde acetal distillation raw liquor finished liquor margin of exposure(MOE)
  • 相关文献

参考文献19

  • 1IARC.Re-evaluation of some organic chemicals,hydrazine and hydrogen peroxide[J].IARC Monographs on the Evaluation of Carcinogenic Risks to Humans,1999,71:319-335.
  • 2LACHENMEIER D W,KANTERES F,REHM J.Carcinogenicity of acetaldehyde in alcoholic beverages:risk assessment outside ethanol metabolism[J].Addiction,2009,104(4):533-550.
  • 3GONCALVES L M,MAGALHAES P J,VALENTE I M,et al.Analysis of aldehydes in beer by gas-diffusion microextraction:characterization by high-performance liquidchromatography-diode-array detection-atmospheric pressure chemical ionization-mass spectrometry[J].Journal of Chromatography A,2010,1 217(24):3 717-3 722.
  • 4PAIANO V,BIANCHI G,DAVOLI E,et al.Risk assessment for the Italian population of acetaldehyde in alcoholic and non-alcoholic beverages[J].Food Chemistry,2014,154:26-31.
  • 5熊绪杰,叶发兵,黄春保.1,3,5,7-四甲基-8-丙酰肼-二氟化硼-二吡咯甲烷柱前衍生高效液相色谱测定白酒中的脂肪醛[J].分析测试学报,2011,30(4):401-406. 被引量:2
  • 6LACHENMEIER D W,SOHNIUS E M.The role of acetaldehyde outside ethanol metabolism in the carcinogenicity of alcoholic beverages:evidence from a large chemical survey[J].Food and chemical toxicology,2008,46(8):2 903-2 911.
  • 7SECRETAN B,STRAIF K,BAAN R,et al.A review of human carcinogens—Part E:tobacco,areca nut,alcohol,coal smoke,and salted fish[J].The Lancet Oncology,2009,10(11):1 033-1 034.
  • 8MIYAKE T,SHIBAMOTO T.Quantitative analysis of acetaldehyde in foods and beverages[J].J Agric Food Chem,1993,41(11):1 968-1 970.
  • 9LIU S Q,PILONE G J.An overview of formation and roles of acetaldehyde in winemaking with emphasis on microbiological implications[J].International Journal of Food Science and Technology,2000,35(1):49-61.
  • 10http://www.inchem.org/documents/jecfa/jecmono/v48je17.htm.

二级参考文献77

  • 1李大和.提高新型白酒质量的技术关键[J].酿酒科技,2005(6):21-27. 被引量:22
  • 2余有贵,曾传广,陈祥斌,李小芳,马立群.CO_2超临界提取双轮底酒醅中香味成分的工艺研究[J].中国酿造,2006,25(11):31-33. 被引量:4
  • 3YU A N, SUN B G, TIAN D T, QU W Y. Analysis of volatile compounds in traditional smoke-cured bacon(CSCB) with different fiber coatings using SPME[J]. Food Chem, 2008, 110( 1 ) : 233 -238.
  • 4YOU J, ZHANG H, SHI Y, ZHAO X, CHEN X. Development of a sensitive fluorescent derivatization reagent 1, 2- benzo-3, 4-dihydrocarbazole-9-ethoxy-carbonylhydrazine and its application for determination of aldehydes from alcoholic beverage using high-perfmlnance liquid chromatography with fluorescence detection and enhance mass spectrometric identification[J]. Talanta, 2005, 66(4) : 982 - 992.
  • 5ROOZEN J P, FRANKEL E N, KINSELLA J E. Enzymic and autoxidation of lipids in low fat foods: model of linoleic acid in emulsified hexadecane[ J]. Food Chem, 1994, 50( 1 ) : 33 -38.
  • 6ANNOVAZZI L, CATTANEO V, VIGLIO S, PERANI E, ROTA C, PECORA F, CETFA G,SILVESTRI M, IADA- ROLA P. High-performance liquid chromatography and capillary electrophoresis: Methodological challenges for the deterruination of biologically relevant low-aliphatic aldehydes in human saliva[ J ]. Electrophoresis, 2004, 25 (9) : 1255 - 1263.
  • 7ZHANG H J, HUANG J F, WANG H, FENG Y Q. Determination of low-aliphatie aldehyde derivatizatives in human sa- liva using polymer monolith microextraetion coupled to high-periormance liquid chromatography [J]. Anal Chim Aeta, 2006, 565(2) : 129 - 135.
  • 8I,l Z, KOZLOWSK1 B M, CHANG E P. Analysis of aldehydes in exeipients used in liquid/semi-s01id formulations by gas chromatographynegative ehemieat ionization mass spectrometry[ J ]. J Chromatogr: A, 2007, 1160(1/2) : 299- 305.
  • 9SALASPURO M P. Acetaldehyde, microbes and cancer of the digestive tract[J]. Rev Clin Lab Sei, 2003, 40(2) : 183 - 185.
  • 10LEEUWEN S M, HENDRIKSEN L, KARST U. Determination of aldehydes and ketones using derivatization with 2, 4- dinitrophenylhydrazine and liquid chromatography/atmospheric pressure photoionization- mass spectrometry[ J]. J Chromatogr: A, 2004, 1058(1/2): 107-112.

共引文献73

同被引文献602

引证文献35

二级引证文献276

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部