期刊文献+

助剂改性FeOOH及其煤直接液化催化活性 被引量:10

Promoters modified FeOOH and their catalytic performances for direct coal liquefaction
下载PDF
导出
摘要 采用共沉淀法分别引入Si、Al、La、Ca、Mg、Zr、Cu、Ni和Co 9种助剂元素对Fe OOH催化剂改性,借助BET、XRD、SEM手段表征各助剂对催化剂微观结构、晶相和形貌的影响,在0.5 L高压釜内测试各催化剂对神东煤的直接液化催化活性。结果表明,引入Si、Al、Ca、Zr、Ni、Co能改善催化剂比表面积和分散度,分别提高煤液化油收率0.7-2.7个百分点;Ni和Co为最优助剂,Mg没有促进作用,Cu、La降低了油收率。研究表明,Al、Ca、Zr是通过结构支撑改善催化剂的织构性质,促进生成易于转化为活性相的小晶粒γ-Fe OOH,Ni、Co主要起到电子型助剂作用,通过强化对氢气的活化,促进煤的转化,提高油收率。 Modified FeOOH catalysts were prepared by a co-precipitation method using Si, Al, La, Ca, Mg, Zr, Cu, Ni and Co as promoters, respectively. The effects on microstructures, crystalline phase and morphology of the catalysts were characterized by BET, XRD and SEM. Their catalytic performances for the direct liquefaction of Shendong coal were evaluated in a 0.5 L stirring autoclave. The results showed that these promoters(Si, Al, Ca, Zr, Ni and Co) could improve the dispersion of the catalysts and surface area, and then improve the catalytic performances for direct coal liquefaction. Increasing by 0.7%—2.7% oil yield over the unmodified the catalyst could be obtained. However, Mg showed no effect on catalytic ability, while Cu and La reduced the Oil yield. The result indicated that Si, Al, Ca and Zr as the structure promoters could significantly improve the texture properties of catalysts, resulting in an increase of γ-FeOOH crystalline phase with small size which was beneficial to form active phase(Fe1-xS). Co and Ni as the electronic promoters could activate H2 preferentially to promote liquefaction, leading to the rising in oil yield.
出处 《化工学报》 EI CAS CSCD 北大核心 2016年第5期1892-1899,共8页 CIESC Journal
基金 神华集团科技创新项目(MZY-13-12)
关键词 煤直接液化 FeOOH催化剂 改性 助剂 共沉淀 油收率 direct coal liquefaction FeOOH catalyst modify promoter co-precipitation oil yield
  • 相关文献

参考文献6

二级参考文献40

  • 1张玉卓.中国神华煤直接液化技术新进展[J].中国科技产业,2006(2):32-35. 被引量:40
  • 2Dadyburjor D, Liu Z. Coal liquefaction in kirk-othmer encyclopedia of chemical technology Volume 6[M]. Fifth edition, Hoboken, New Jersey: Witey-Interscience, John Wiley & Sons, Inc., 2004: 832-869.
  • 3高晋生,张德祥煤直接液化技术[M].北京:化学工业出版社,2004.
  • 4Coat: Energy for the Future[C]// Committee on the Strategic Assessment of the US Department of Energies Coal Program, Nation Research Council, 1995: 102.
  • 52008年中国石油进口依存度接近52%[OL].中国经济网,[2009-02-10]. http ://www.ce.cn/cysc/newmainllist/ny/200902/10/t20090210_18164225.shtml.
  • 62007年中国石油进口量近2亿吨,进口步伐呈现超速度[OL].[2008-03-02]. news.xinhuanet.com/fortune/2008-03/02/content_7699408, htm.
  • 7Fletcher J, Sun Q, Bajura R, et al. Coal to Clean Fuel - The Shenhua Investment in Direct Coal Liquefaction[C]//Twenty-First Annual International Pittsburgh Coal Conference, Sept. 13-17, 2004, Osaka, Japan.
  • 8NolanP, ShiomanA, RuiH, Coal liquefaction, ShenhuaGroup, and China's Energy Security[J]. European Management Journal, 2004, 22: 150-164.
  • 9Liu Z, Shi S, Li Y. Coal liquefaction technologies--Development in China and challenges in chemical reaction engineering[J]. Chemical Engineering Science, 2010, 65(1): 12-17.
  • 10Liu Z, Shi S, Li Y. Coal liquefaction technologies--Development in China and challenges in chemical reaction engineering[C]//The 20th International Symposium on Chemical Reaction Engineering (ISCRE20), Plenary Lecture, Kyoto, Japan, Sept. 10, 2008.

共引文献114

同被引文献91

引证文献10

二级引证文献25

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部