摘要
电催化析氢反应作为一种绿色、可持续的制备氢气方法,受到了广泛关注.近年来,非贵金属析氢催化剂以其低成本和相对高的催化活性取得了较快的研究进展,其中,钼基纳米催化剂目前已成为电催化析氢中最受关注的研究热点之一.本文综述了钼基碳化物、磷化物、氮化物以及硫化物在电催化析氢反应中的催化机理和研究进展,分析了提高析氢催化活性的方法,并对钼基非贵金属催化剂的发展趋势进行了展望.
Electrochemical catalytic production of hydrogen has been considered as a promising and sustainable strategy for clean and renewable energy technologies. Molybdenum-based non noble metal catalysts for the hydrogen evolution reaction have attracted extensive attention due to its effective catalytic performance. In this review, the recent progresses in molybdenum-carbide,phosphide, nitride and sulfide electrocatalysts are presented. In addition, the strategies to improve the catalytic performance are analyzed and the prospects for the future development trends are expected.
出处
《电化学》
CAS
CSCD
北大核心
2016年第2期192-204,共13页
Journal of Electrochemistry
基金
国家自然科学基金项目(No.21306060,No.21573083)
教育部新世纪优秀人才支持计划(No.NCET 130237)资助
关键词
析氢反应
电催化
钼基材料
纳米颗粒
hydrogen evolution reaction
electrocatalysis
molybdenum-based materials
nanoparticles
