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Effect of molecular structure and slump loss resistance of polycarboxylate superplasticizers on self-compacting concrete

Effect of molecular structure and slump loss resistance of polycarboxylate superplasticizers on self-compacting concrete
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摘要 A new kind of polycarboxylate superplasticizer with high slump loss resistance was obtained by designing scheduled molecular structure.The number average molecular mass of the polymer was characterized by the gel permeation chromatography measurements.And chemical structure of the polymer was observed by the Fourier transform infrared spectroscopy(FT-IR).The results show that the good workable maintaining of self-compacting concrete could be achieved through direct adjustment of number average molecular mass and different unsaturated monomer in synthetic process.The FT-IR analysis illustrated that the high slump loss resistance of polycarboxylate superplasticizers with ester and carboxyl group and expectations of molecular structure were designed. A new kind of polycarboxylate superplasticizer with high slump loss resistance was obtained by designing scheduled molecular structure. The number average molecular mass of the polymer was characterized by the gel permeation chromatography measurements. And chemical structure of the polymer was observed by the Fourier transform infrared spectroscopy (FT-IR). The results show that the good workable maintaining of self-compacting concrete could be achieved through direct adjustment of munber average molecular mass and different unsaturated monomer in synthetic process. The FT-IR analysis illustrated that the high slump loss resistance of polycarboxylate superplasticizers with ester and carboxyl group and expectations of molecular structure were designed.
作者 兰自栋
出处 《Journal of Chongqing University》 CAS 2016年第1期35-42,共8页 重庆大学学报(英文版)
关键词 high slump loss resistance of polycarboxylate superplasticizers self-compacting concrete number average molecular mass WORKABILITY high slump loss resistance of polycarboxylate superplasticizers self-compacting concrete number average molecular mass workability
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