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Microwave-assisted One-pot Synthesis of Ag NPs/C and Its Application in H2O2 and Glucose Detection

Microwave-assisted One-pot Synthesis of Ag NPs/C and Its Application in H2O2 and Glucose Detection
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摘要 The facile preparation of Ag NPs/C via a one-pot strategy was carried out by microwave treatment of a mixed aqueous solution of AgNO3 and glucose at 180 ℃ for 20 min without the presence of extra reducing agent. The as-synthesized Ag NPs/C showed high catalytic performance toward the reduction of H2O2. The H2O2 sensor constructed with as-synthesized Ag NPs/C exhibited a short amperometric response time of less than 2 s. The linear range was approximately (0.1-50) mmol/L(r=0.997), and the detection limit was approximately 3.3 μmol/L at a signal-to-noise ratio of 3. A glucose biosensor was fabricated by immobilizing glucose oxidase onto Ag NPs/C- modified glassy carbon electrode to detect glucose. The glucose sensor had a wide linear response range of 2-22 mmol/L(r=0.999) and a detection limit of 190 μmol/L. The facile preparation of Ag NPs/C via a one-pot strategy was carried out by microwave treatment of a mixed aqueous solution of AgNO3 and glucose at 180 ℃ for 20 min without the presence of extra reducing agent. The as-synthesized Ag NPs/C showed high catalytic performance toward the reduction of H2O2. The H2O2 sensor constructed with as-synthesized Ag NPs/C exhibited a short amperometric response time of less than 2 s. The linear range was approximately (0.1-50) mmol/L(r=0.997), and the detection limit was approximately 3.3 μmol/L at a signal-to-noise ratio of 3. A glucose biosensor was fabricated by immobilizing glucose oxidase onto Ag NPs/C- modified glassy carbon electrode to detect glucose. The glucose sensor had a wide linear response range of 2-22 mmol/L(r=0.999) and a detection limit of 190 μmol/L.
出处 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2016年第3期433-436,共4页 高等学校化学研究(英文版)
基金 Supported by the National Natural Science Foundation of China(No.21175129), the National Basic Research Program of China(No.2011CB935800) and the Scientific and Technological Development Plan Project of Jilin Province, China(No. 20100534).
关键词 Carbon Ag nanoparticles Microwave H2O2 GLUCOSE Carbon Ag nanoparticles Microwave H2O2 Glucose
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