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硫/氧化石墨烯锂硫电池电极材料的制备与性能表征

Synthesis and characterization of H-GO / S composites as cathode materials for lithium / sulfur batteries
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摘要 以改进Hummers法制备的氧化石墨烯作为载体,运用简单化学沉积并加以热处理制备硫/氧化石墨烯(H-GO/S)复合材料。采用傅里叶红外光谱仪(FT-IR)、X线衍射仪(XRD)、透射电子显微镜(TEM)、热质量分析仪(TGA)等表征手段对H-GO/S复合材料的微观结构、形貌和组成进行表征;同时运用恒流充放电和循环伏安对电极材料进行电化学性能测试。在0.1 C倍率下H-GO/S复合材料首次放电比容量达1 060 m A·h/g,20次循环之后,放电比容量趋向稳定,160次循环后放电比容量仍可达到620 m A·h/g,衰减率仅为0.068%,库伦效率始终保持在97%以上。以上结果表明H-GO/S复合材料具有优良的循环稳定性以及比较高的库伦效率。 The graphene oxide( GO) was synthesised by promoted Hummers process. S deposed on GO through an uncomplicated chemical reaction,then heat treated the assynthesized samples to prepare HGO / S composites. The microstructure and the morphology of the composited electrode were characterized by X-ray diffraction( XRD),transmission electron microscope( TEM) and thermogravimetric analysis( TGA). The electrochemical properties of the electrodes were investigated by galvanostatic charge-discharge and cyclic voltammetry( CV). The H-GO / S composited electrodes manifested a high initial capacity( 1 060 m A·h / g,0. 1 C) and excellent capacity stability after 20 cycles.The discharge capacity could retain 620 m A·h / g even after 160 cycles,corresponding to an extremely low capacity decay rate of0. 068% per cycle.The average coulombic efficiency was above 97%. Results showed that the H-GO / S composited electrodes had excellent cyclability and high coulumbic efficiency.
出处 《南京工业大学学报(自然科学版)》 CAS 北大核心 2016年第4期17-20,27,共5页 Journal of Nanjing Tech University(Natural Science Edition)
基金 江苏省自然科学基金重点资助项目(BK2011030) 江苏省教育厅重点项目(KJA430006) 江苏高校优势学科建设工程
关键词 锂硫电池 正极材料 热复合 H-GO/S复合材料 循环稳定性 lithium / sulfur batteries cathode materials melt-diffusion H-GO / S composite stable cycle performance
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