摘要
乙丙橡胶以其独特的性能,在汽车工业、建筑行业、油品添加剂、塑胶跑道等领域有广泛的应用。本文主要介绍了乙丙橡胶生产技术、乙丙橡胶产品牌号、性能以及应用领域,结合现有的乙丙橡胶科研情况,阐述了乙丙橡胶催化剂的研发、核壳型球状乙丙橡胶、原位聚合法合成长链支化乙丙橡胶、乙烯、丙烯与其他二烯烃的共聚物研究进展;详细研究了乙丙橡胶溶液聚合工艺技术中的聚合技术、单体回收技术、失活洗涤技术、闪蒸提浓技术以及国外公司在中国建设装置的生产技术情况。提出了乙丙橡胶的关键生产技术是乙丙橡胶聚合所采用的催化剂体系,通过催化体系的更新换代,开发不同用途的乙丙橡胶,以满足开发高性能材料的要求。在此基础上,指出了今后乙丙橡胶新的催化体系开发将成为未来的研究重点。
Ethylene propylene diene monomer（EPDM）has wide applications in the auto industry, construction industry,oil additives,plastic runwayetc. due to its unique performance. This article summarizes the production technology of EPDM,and its grades,performance and applications. Based on the existing EPDM researches,the development of catalyst for EPDM,core-shell structure spherical EPDM,long chain branched EPDM bysitu polymerization,and the copolymer by ethylene and propylene and other dienes are expounded. Meanwhile,the polymerization technology,monomer recovery technology,deactivation washing technology,and flash concentration technology in the solution polymerization of EPDM and the plant production technology of a foreign company in China are studied in detail. It puts forward that the key in the production of EPDM is the polymerization catalyst system. By the upgrading of catalysts,we could produce EPDM with different functions so as to meet the demand of high-performance materials. So,it points out that the development of new catalytic system will become one research focus in the future.
出处
《化工进展》
EI
CAS
CSCD
北大核心
2016年第8期2317-2322,共6页
Chemical Industry and Engineering Progress
