摘要
An enhanced adsorption and desorption procedure of Cu(II) onto green synthesized acrylic acid grafted polytetrafluoroethylene fiber(i.e. AA-PTFE) was conducted with various chemical methods. The results show that the optimal adsorption condition is in acetic acid, sodium acetate(HAc-Na Ac) buffer solution(p H=6.80) with the initial concentration of 0.2 mg/mL. The process is very fast initially and equilibrium time is 12 h with a high Cu(II) uptake of 112.26 mg/g at 298 K. Various thermodynamic parameters indicate that the adsorption process is spontaneous and endothermic in nature. In the elution test, 2 mol/L HCl solution achieves satisfactory elution rate and shows no significant decrease after 5 adsorption-desorption cycle, which indicates that AA-PTFE can be regenerated and reused, and due to which a reasonable amount of nondegradable polymer material is avoided in industrial use. Finally, PTFE, AA-PTFE fiber, and Cu(II) loaded AA-PTFE fiber were characterized with various techniques, including IR spectroscopic technique, SEM and EDS.
An enhanced adsorption and desorption procedure of Cu（II） onto green synthesized acrylic acid grafted polytetrafluoroethylene fiber（i.e. AA-PTFE） was conducted with various chemical methods. The results show that the optimal adsorption condition is in acetic acid, sodium acetate（HAc-Na Ac） buffer solution（p H=6.80） with the initial concentration of 0.2 mg/mL. The process is very fast initially and equilibrium time is 12 h with a high Cu（II） uptake of 112.26 mg/g at 298 K. Various thermodynamic parameters indicate that the adsorption process is spontaneous and endothermic in nature. In the elution test, 2 mol/L HCl solution achieves satisfactory elution rate and shows no significant decrease after 5 adsorption-desorption cycle, which indicates that AA-PTFE can be regenerated and reused, and due to which a reasonable amount of nondegradable polymer material is avoided in industrial use. Finally, PTFE, AA-PTFE fiber, and Cu（II） loaded AA-PTFE fiber were characterized with various techniques, including IR spectroscopic technique, SEM and EDS.
基金
Project(20133326110006)supported by Ph D Programs Foundation of Ministry of Education of China
Project(2005002)supported by Zhejiang Provincial Key Laboratory of Fiber Materials and Manufacturing Technology,China
Project(YR2015002)supported by Zhejiang Provincial Top Key Academic Discipline of Chemical Engineering and Technology of Zhejiang Sci-Tech University,China
