摘要
通过羟基铁对钠基膨润土插层改性制备了羟基铁插层膨润土(OH—Fe-Bent),用于去除废水中的U(VI)。实验考察了pH值、U(VI)初始浓度、温度和吸附时间对OH—Fe-Bent吸附U(VI)效果的影响,并进行吸附动力学和热力学分析。采用FTIR、SEM、XRD等手段分析相关吸附机制。实验结果表明:OH—Fe-Bent吸附U(VI)的最佳pH为4,在温度为15℃,投加量为0.8g/L,U(VI)初始浓度为10 mg/L时,OH—Fe-Bent对U(VI)的去除率达到99.55%,吸附平衡时间为90min。Langmuir等温吸附模型和准二级动力学模型(相关系数的平方约为1)均可较好地拟合其吸附过程,理论饱和吸附量可达97.09mg/g,OH—Fe-Bent对U(VI)是单分子层吸附。FTIR、SEM分析表明OH—Fe-Bent吸附U(VI)后自身结构没有改变,XRD分析表明羟基铁已经成功插入膨润土层间。
Hydroxyl Fe intercalated bentonite（OH—Fe-Bent）was prepared by Na-bentonite while using hydroxyl Fe as intercalated material.The synthesized OH—Fe-Bent composites applied to adsorb U（VI）from water solution.The effects of pH value,initial U（VI）concentration,temperature and contact time on adsorption of U（VI）for OH—Fe-Bent were experimentally determined,and the process of adsorption was investigated by kinetic and thermodynamic analysis.The corresponding adsorption mechanisms were analyzed by FTIR,SEM,and XRD etc.The experimental results indicate that the maximum adsorption capacity occurs at pH 4and the removal rate of U（VI）for OH—Fe-Bent reaches 99.55%for initial U（VI）concentration of 10mg/L and adsorbent dosage of 0.8g/L at15 ℃.Meanwhile the adsorption reaches equilibrium within 90 min.The adsorption process fits well with the Langmuir isotherm adsorption model and pseudo second-order kinetic model（square of correlation coefficient is about 1）,and the theoretical saturated adsorption capacity is 97.09mg/g,adsorption mechanism of U（VI）for OH—Fe-Bent is a monolayer adsorption.The FTIR and SEM analyses show that the structure of OH—Fe-Bent has no change after absorbing U（VI）and the XRD analysis shows that the hydroxyl Fe has already intercalated bentonite.
作者
陈婧
谢水波
曾涛涛
凌辉
王亮
CHEN Jing XIE Shuibo ZENG Taotao LING Hui WANG Liang(Hunan Province Key Laboratory of Pollution Control and Resources Reuse Technology, University of South China, Hengyang 421001, China Key Discipline Laboratory for National Defence for Biotechnology in Uranium Mining and Hydrometallurgy, University of South China, Hengyang 421001, China)
出处
《复合材料学报》
EI
CAS
CSCD
北大核心
2016年第11期2649-2656,共8页
Acta Materiae Compositae Sinica
基金
国家自然科学基金(11175081
11475080)
高等学校博士点基金(20134324110003)
2015湖南省研究生科研创新项目(CX2015B405)
关键词
羟基铁
插层
膨润土
吸附
铀
hydroxyl Fe
intercalate
bentonite
adsorption
uranium
