期刊文献+

聚酯薄膜用丙烯酸酯乳液的制备及性能

Preparation and Properties of Acrylate Emulsion for Polyethylene Terephthalate
下载PDF
导出
摘要 采用无皂乳液聚合法,以过硫酸铵为引发剂制备了丙烯酸酯乳液,将其涂覆在聚酯薄膜表面,考查对薄膜附着力的影响。研究了聚合反应温度、软硬单体配比、乳化剂用量、中和剂等对乳液性能和薄膜附着力的影响。结果表明:反应温度为80℃,乳化剂用量为1.5%,w(EA)∶w(MMA)为2∶3,使用氨水和N,N-二甲基乙醇胺为混合中和剂,得到了性能最佳的乳液,薄膜附着力达到100。采用红外光谱(FT-IR)、粒度仪对树脂结构和性能进行了分析表征。 Arylate emulision was synthesized by soap-free emulsion polymerization, with ammonium persuttate as initiator, the surface of polyethylene terephthalate (PET) was coated by this emulsion, and its effect on film adhesion was investigated. The reaction temperature, the mass ratio of soft to hard monomer, emulsifier amount and neutralizer were discussed, which decided the film adhesive force. The results showed that:the reaction temperature was 80 ℃, the emulsifier was 1.5%wt, the mass ratio of MMA to EA was 2 : 3, ammonia and N, N-dimethyl ethanolamine were used as neutralizer, the optimal emulsion was obtained, the adhesive force of PET was 100. The structure and composition of resin were analyzed by FT-IR and particle size analyzer.
作者 安佳丽 周守发 王辉 王旭亮 AN Jia-li ZHOU Shou-fa WA NG Hui WANG Xu-liang(Hefei Lucky Science & Technology Industry Company Ltd., Hefei 230041, China)
出处 《安徽化工》 CAS 2016年第6期46-49,共4页 Anhui Chemical Industry
关键词 聚酯薄膜 UV胶 丙烯酸酯 无皂乳液 polyethylene terephthalate UV adhesive acrylate soap-free emulsion
  • 相关文献

参考文献10

二级参考文献86

共引文献125

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部