摘要
利用溶剂热脱水法合成了新型乙酸锌配位聚合物[Zn(CH_3COO)_2],通过元素分析,红外光谱,X-射线粉末衍射和X-射线单晶衍射对配合物的结构进行了表征。X-射线单晶衍射结果表明配合物中每个锌与来自四个不同乙酸中的四个氧配位形成了ZnO_4四面体结构进而形成了具有lvt拓扑结构的三维结构。
A novel zinc coordination polymer Zn（CH3COO）2 was prepared under temperature-controlled solvo-thermal dehydration.The structure was characterized by elemental analysis,IR,XRD and single crystal X-ray diffraction.X-ray single-crystal diffractions revealed that the compound is three-dimensional（3D） frameworks.Each Zn（ Ⅱ） is coordinated with four oxygen atoms from four separate acetato anions to show a ZnO4 tetrahedron that exhibits the net topology of lvt.
出处
《当代化工》
CAS
2016年第12期2754-2756,共3页
Contemporary Chemical Industry
关键词
乙酸锌
配位聚合物
晶体结构
zinc（Ⅱ） acetate
coordination polymer
crystal structure
